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  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 112 (2000), S. 1721-1732 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The electronically chemiluminescent reaction Mn+O3→MnO*+O2 was investigated using a beam-gas configuration. Light from the MnO A 6∑+–X 6∑+ transition was collected by a charge coupled device (CCD) array detector with resolutions of 0.5 and 0.1 nm. The spectrum at lower resolution (500–655 nm) encompassed the Δv=−3 to +2 sequences, while that at higher resolution (555.5–583.5 nm) encompassed only the Δv=0 sequence. These two spectra were separately fitted with a nonlinear least-squares program to obtain vibrational and rotational distributions of the nascent MnO*. The limited vibrational-state coverage of the higher-resolution spectrum made it unrealiable for determining the vibrational state distribution, and it was useful only for characterizing the rotational distribution when v′=0. The best-fit vibrational excitation is somewhat less than for the Prior model, but the rotational excitation is considerably greater. A consideration of the electronic structure of reactants and products indicates that principal changes occurring in the chemiluminescent reaction are σ–electron donation from the sdz2 hybridized Mn orbital to the O3 lowest unoccupied molecular orbital (LUMO) (2b1) and π–electron backdonation from the O–O 4b2 orbital to the Mn 3dπ orbital. Correlation of the orbitals involved indicates that direct access is allowed to the MnO A 6∑+(10σ*18σ1) state. This mechanism favors Mn approach perpendicular to the O3 plane and suggests that the product's rotational excitation may originate in O2–OMn repulsion arising from removal of electron density from the slightly bonding 4b2 orbital of O3. However, some rotational excitation could also be attributed to conservation of angular momentum arising from a sizable reactive impact parameter. The lack of significant vibrational excitation is a consequence of the short-range nature of the partial charge transfer in this reaction channel. © 2000 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 70 (1999), S. 3397-3401 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: Equipment is described which provides measurements of the pressure and volume of unidirectional liquid flow through sample cores of porous solids. The real-time measurement of flow pressures enables any changes in conductivity resulting either from interactions with the flow liquid or from changes in effective stress levels to be monitored directly. The equipment can use a range of flow liquids and be adapted for miscible and immiscible displacement studies. It is particularly suitable for cement-based and stone construction materials. © 1999 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1089-7674
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Implosions of direct-drive, deuterium–tritium (DT) gas-filled plastic capsules are studied using nuclear diagnostics at the OMEGA laser facility [T. R. Boehly et al., Opt. Commun. 133, 495 (1997)]. In addition to traditional neutron measurements, comprehensive sets of spectra of deuterons, tritons, and protons elastically scattered from the fuel and shell by primary DT neutrons ("knock-on" particles) are, for the first time, obtained and used for characterizing target performance. It is shown with these measurements that, for 15-atm DT capsules with 20-μm CH shells, improvement of target performance is achieved when on-target irradiation nonuniformity is reduced. Specifically, with a two-dimensional (2D) single-color-cycle, 1-THz-bandwidth smoothing by spectral dispersion (SSD), plus polarization smoothing (PS), a primary neutron yield of ∼1×1013, a fuel areal density of ∼15 mg/cm2, and a shell areal density of ∼60 mg/cm2 are obtained; these are, respectively, ∼80%, ∼60%, and ∼35% higher than those achieved using 0.35-THz, 3-color-cycle, 2D SSD without PS. (In determining fuel areal density we assume the fuel to have equal numbers of D and T.) With full beam smoothing, implosions with moderate radial convergence (∼10–15) are shown to have ρR performance close to one-dimensional-code predictions, but a ratio of measured-to-predicted primary neutron yield of ∼0.3. Other capsules that are predicted to have much higher radial convergence (3.8-atm DT gas with 20-μm CH shell) are shown to have ρRfuel∼3 mg/cm2, falling short of prediction by about a factor of 5. The corresponding convergence ratios are similar to the values for 15-atm capsules. This indicates, not surprisingly, that the effects of mix are more deleterious for high-convergence implosions. A brief comparison of these moderate- and high-convergence implosions to those of similar deuterium–deuterium (D2) gas-filled capsules shows comparable hydrodynamic performance. © 2001 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 68 (1997), S. 4555-4560 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: A diagnostic which combines a quartz crystal microbalance (QCM) and a gridded energy analyzer has been developed to measure the metal flux ionization fraction in a modified commercial dc magnetron sputtering device. The sensor is mounted on a linear motion feedthrough and embedded in a slot in the substrate plane to allow for measuring the uniformity in deposition and ionization throughout the plane of the wafer. Radio-frequency (rf) power is introduced through a coil to ionize the Al atoms. The metal flux ionization fraction at the QCM is determined by comparing the total deposition rate with and without a bias that screens out the ions, but that leaves the plasma undisturbed. By varying the voltage applied to the grids, the plasma potential is determined. At a pressure of 35 mTorr, a magnetron power of 2 kW, and a net rf power of 310±5 W, 78±5% ionization was found. © 1997 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: A model independent method to determine fuel 〈ρR〉 is to measure the energy spectrum and yield of elastically scattered primary neutrons in deuterium–tritium (DT) plasmas. As is the case for complementary methods to measure fuel 〈ρR〉 (in particular from knock-on deuterons and tritons [S. Skupsky and S. Kacenjar, J. Appl. Phys. 52, 2608 (1981); C. K. Li et al. (unpublished)]), minimizing the background is critical for successful implementation. To achieve this objective, a novel spectrometer for measurements of neutrons in the energy range 10–18 MeV is proposed. From scattered neutrons (10–13 MeV), the DT fuel 〈ρR〉 will be measured; from primary neutrons (∼14 MeV), the ion temperature and neutron yield will be determined; and from secondary neutrons, in the energy range 12–18 MeV, the fuel 〈ρR〉 in deuterium plasmas will be inferred at the National Ignition Facility. The instrument is based on a magnetic spectrometer with a neutron-to-deuteron (nd) conversion foil for production of deuteron recoils at nearly forward scattered angles. In its initial phase of implementation, CR-39 track detectors will be used in the focal plane to detect the recoil deuterons with extremely high spatial resolution. Besides simplicity, CR-39 track detectors will facilitate a highly accurate energy calibration. However, in a later implementation of the spectrometer design, the recoils will also be detected by an array of fast scintillation counters functioning in current mode. In either detection scheme, the detection efficiency is about 10−9 for measuring 14 MeV neutrons with an energy resolution of about 3%. Due to its large dynamic range, its relatively high efficiency, and a compliant design that allows for significant background rejection, this spectrometer can be effectively used, with very high resolution, at both OMEGA and the National Ignition Facility. © 2001 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 6
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    Cambridge : Periodicals Archive Online (PAO)
    The Modern language review. 63:1 (1968:Jan.) 146 
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 18 (1999), S. 1925-1927 
    ISSN: 1573-4811
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Primates 19 (1978), S. 537-550 
    ISSN: 0032-8332
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Five primate species were observed in an 83 hectare study site in northern Colombia. They wereAlouatta seniculus, Aotus trivirgatus, Ateles belzebuth hybridus, Cebus albifrons, andSaguinus leucopus. Average group size for the four diurnal species ranged from 5.3 individuals per sighting forCebus to 3.3 forAlouatta andAteles. BecauseCebus utilized regenerating forest, mature stands as well as cultivated sectors, they were able to use 30% more of the study site than the larger cebids. Monkey sightings along transects peaked at 0600–0800 and 1500–1800 and were lowest between 0900–1300 for the four diurnal cebids. The hourly rate of sighting the large cebids was 2–3 times greater for the point method than the transect method, but was less forCebus andSaguinus. However, consistently higher crude density estimates were obtained by the transect method than by the point method. As expected, there was less discrepancy between census methods for the large cebids which regularly utilized the upper canopy. The point method was barely 20% as effective as the transect method for estimating crude densities ofCebus andSaguinus. Factors influencing the effectiveness of the two census techniques as monkey detection and visibility, climatic conditions, and length of study are discussed. Recommendations for improving censusing effectiveness are listed.
    Type of Medium: Electronic Resource
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