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  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 86 (1987), S. 1235-1248 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: A photoionization mass spectrometric study of SiH4 at T=150 K reveals the presence of SiH+4 with an adiabatic threshold at 11.00±0.02 eV. The implications for the structure of this Jahn–Teller split state are discussed. The appearance potentials of SiH+2 and SiH+3 are 11.54±0.01 eV and ≤12.086 eV, respectively. The reaction of F atoms with SiH4 generates SiH3 (X 2A1), SiH2 (X 1A1 and a 3B1), and SiH (X 2Π) in sufficient abundance for photoionization studies. The measured adiabatic ionization potentials (eV) are: SiH3, 8.01±0.02; SiH2 (X 1A1), 9.15±0.02 or 9.02±0.02; SiH2 (a 3B1), 8.244±0.025; SiH, 7.91±0.01. The singlet–triplet splitting in SiH2 is either 0.78±0.03 or 0.91±0.03 eV. The dissociation energy of SiH is 2.98±0.03 eV. A Rydberg series is observed, converging to SiH+ (a 3Π) at 10.21±0.01 eV. Heats of formation of the various neutral and ionic species are presented, as are the stepwise bond energies of SiH4.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 85 (1986), S. 4815-4824 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The photoion yield curve of SeH, prepared by the reaction H+H2Se is presented. The adiabatic I.P. is 9.845±0.003 eV, and autoionization structure is observed, from which higher I.P.'s are inferred. The photoion yield curves of H2Se+, SeH+, and Se+ from H2Se are also measured. The fragmentation thresholds, together with I.P. (SeH), enable one to infer the bond energies D0(HSe−H)=78.99±0.18 kcal/mol and D0(SeH)=74.27±0.23 kcal/mol. The adiabatic I.P. for H2Se (X˜ 2B) is 9.886±0.003 eV.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 86 (1987), S. 674-676 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The adiabatic ionization potential of CD4 is measured by photoionization mass spectrometry to be 12.658±0.015 eV, which is 0.05±0.02 eV higher than that of CH4. The difference is attributed to zero point energy differences, rather than different Jahn–Teller stabilization energies.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: Reactions with a heavy projectile incident on a light target can be used for the efficient in-flight production of secondary radioactive beams. An overview of this technique is given using data on 17F beams produced via the p(17O, 17F)n and d(16O, 17F)n reactions. With primary 16,17O beam currents of 100 pnA, intensities of up to 2×106 17F/s on target were achieved. Using this beam, the p(17F,α)14O reaction was measured. © 2000 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 66 (1995), S. 2883-2887 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: A direct ion plasma sputtering effect has been observed in an electron cyclotron resonance ion source and developed into a reliable and simple method for producing ion beams from some solid materials. We describe the ion sputtering technique used with the Argonne Tandem Linac Accelerator System Positive Ion Injector Electron Cyclotron Resonance ion source to produce, to date, stable beams of nickel, silver, tellurium, gold, lead, and bismuth and present the results obtained in test cases. © 1995 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 6
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: A test stand for development of ion sources for radioactive beams is currently being commissioned at Argonne. It is located at the Physics Division's Dynamitron accelerator which will be used as a neutron generator with a flux of up to 1011 neutrons per second created by reactions of 4 MeV deuterons on various targets with beam currents of up to 100 μA. The primary targets will be located adjacent to heated secondary targets inside an on-line ion source. With this neutron-generator facility it will be possible to produce radioactive beams of various isotopes, such as 6He, 24Na, and neutron-rich fission fragments. For example, with a secondary target of uranium carbide containing 25 g of natural or depleted uranium the yields of individual isotopes in the target will be about 107/s for isotopes such as 132Sn, 140Xe, and 142Cs, near the peak of the fission distribution. The ion sources to be evaluated will be located within a shielded cave with walls consisting of 30 cm of steel plus 60 cm of concrete to attenuate the prompt neutron radiation by a factor of about 104. Secondary beams of radioactive fission fragments with intensities on the order of 106/s per isotope will be extracted in the 1+ charge state at energies of 20 keV and mass separated with a Danfysik mass separator. Light isotopes, such as 6He and 24Na, can be produced via (n,α) and (n,p) reactions on appropriate target materials. Commissioning began with measurements of fission yields from primary targets of C, Be, BeO, and BN. A surface ionization source which is a variation of the one used in the TRISTAN on-line mass seperator facility at Brookhaven National Laboratory has been installed and tested with stable Rb and Cs beams. The isotope separator was also commissioned with these beams. The development program will include emittance measurements and source optimization, initially with stable beams, and target-delay-time and release-efficiency measurements for various target/secondary-beam systems. © 1998 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 7
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The ion yield curves of PH+3, PH+2, and PH+ from photoionization of PH3 have been measured. The free radical PH2 has been generated by pyrolysis, and the ion yield curve of PH+2 (PH2) determined. These measurements yield directly I.P. (PH3)=9.870±0.002 eV, and I.P. (PH2)=9.824±0.002 eV. In addition, we deduce D0 (H2P–H)=82.46±0.46 kcal/mol, D0 (HP–H)=74.2±2 kcal/mol, D0 (P–H)=70.5±2 kcal/mol, I.P. (PH)=10.18±0.1 eV, and other thermochemically related quantities. The ionization energies of PH, PH2, and PH3 are computed by ab initio molecular orbital methods to fourth order in Møller–Plesset theory, and are found to be in good agreement with experiment. The ground state of PH+2 is inferred to be 1A1, with the 3B1 state higher by ≥0.71 eV. This ordering is the reverse of that in CH2 and NH+2.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 83 (1985), S. 4319-4328 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The photoionization mass spectrum of NH2, prepared by the reaction H+N2H4, is presented. The adiabatic ionization potential is 11.14±0.01 eV (0.32 eV lower than reported by PES). A prominent autoionizing Rydberg series is observed, converging to the excited A˜ 1A1 state at 12.445±0.002 eV. By extrapolation, NH2 should absorb strongly at ∼1150 A(ring). From the threshold for formation of NH+ (NH2), we obtain ΔH0f 0(NH+)=396.3±0.3 kcal/mol. With auxiliary data, we compute ΔH0f 0(NH)=85.2±0.4 kcal/mol, ΔH0f 0(NH2)=45.8±0.3 kcal/mol, D0(H2N–H)=106.7±0.3, D0 (HN–H)=91.0±0.5, and D0 (N–H)=79.0±0.4 kcal/mol. Additional photoionization measurements on N2H4 and N2H3 are also included.
    Type of Medium: Electronic Resource
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  • 9
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    Unknown
    London : Periodicals Archive Online (PAO)
    RSA Journal. 124:5234 (1976:Jan.) 52 
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