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  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 88 (1988), S. 3061-3071 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: This work reports the measurements of rate coefficients for excitation transfer reactions of metastable He(2 3S) atoms, produced in 0.3–4 atm of helium, with various reactants presenting a wide range of characteristics. In all cases studied, three-body reaction channels were identified with most probable values of rate coefficients lying in the range from 0.2 to 6.7×10−31 cm6 s−1, for Ne and N2O, respectively. These are generally more than one order of magnitude smaller than previously reported. The interpretation of this discrepancy in terms of a more reactive intermediate He2(Σ*) complex in dynamic equilibrium with the He(2 3S) population seems to be confirmed, and is analyzed in some detail.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 65 (1989), S. 3369-3380 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Measurements and analyses have been made of electron impact ionization and of current growth in pulsed, low-current, prebreakdown discharges in parallel-plane geometry in N2 at very high electric field to gas density ratios E/n and low products of the gas density n and electrode separation d. The E/n range and nd ranges were 1〈E/n〈52 kTd, where 1 Td=10−21 V m2 , and 6×1018 〈nd〈3×1020 m−2 (or 0.02〈pd〈1 Torr cm, where p is pressure) and were below breakdown values. Measurements were made of the transported charge on the time scales of electron transit, ion transit, and metastable decay. Measurements were also made of the growth of steady-state discharge currents as a function of discharge voltage. The contributions of avalanches resulting from ion- and metastable-induced secondary electrons were determined from the ratio of electron-excited N+2 391.4-nm emission integrated over all avalanches to the integrated emission during the laser-initiated electron pulse. Calculations based on ionization by electrons only show good agreement with the measured charge transported during the electron avalanche and with the current multiplication. Analysis of 391.4-nm emission data and of charge transported at E/n≥10 kTd and voltages near breakdown using the assumption of electron impact ionization leads to large apparent secondary electron yields at the cathode which increase significantly with nd. At E/n≥10 kTd, and for the voltages of our experiments, fast N2 produced in charge transfer collisions of N+2 with N2 appears to provide most of the secondary electrons. The apparently small contribution of ionization of N2 by N2, N+2 , N, and N+ is consistent with our assumption that each of these ionization cross sections is equal to that for N2-N2 collisions and so are much smaller than for Ar+ -Ar or Ar-Ar collisions.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 83 (1985), S. 2836-2839 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: This work focuses upon previously encountered problems that have impeded the understanding of the role of He2(3Σu) metastable molecules in the afterglows of electrical discharges into atmospheric pressures of helium containing admixtures of reactants. New data are reported that generally confirm the literature values for the reactivities of this species at high pressures and continue the disagreement with earlier measurements in low pressure plasmas. Results are presented for reactions with HCl and HBr for the first time. A study of systematic dependencies of rates upon molecular parameters is reported which shows that the ratio for bimolecular reactions of vibrationally excited and unexcited He2(3Σu) molecules is largely independent of the identity of the reacting partner. This provides a means for using data on the pressure dependent part of the effective rate of reaction of He(2 3S) atoms to estimate the rate coefficients for the bimolecular reactions of the more elusive He2(3Σu) molecule.
    Type of Medium: Electronic Resource
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