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  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 102 (1995), S. 6949-6952 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: An anisotropic product angular distribution has been observed in the dissociative photodetachment of O−4 at 523 nm. Energy and angular distributions of coincident O2 products from the process O−4+hν→O2+O2+e− were measured using translational energy spectroscopy in a fast ion beam. The angular distribution peaks perpendicular to the electric vector of the laser beam. © 1995 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 70 (1999), S. 2268-2276 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: A new photoelectron–photofragment-coincidence spectrometer is described. Using a multiparticle time- and position-sensitive detector, this apparatus allows the study of dissociation processes of negative ions yielding three photofragments in coincidence with a photoelectron. The photoelectron spectrometer uses two detectors and works in time of flight mode, detecting 10% of the photoelectrons with an energy resolution of 5% at 1.3 eV as shown in studies of the photodetachment of O2−. A third detector is used for collection of multiple photofragments (up to 8) in coincidence. This multiparticle detector uses a crossed-delay-line anode and fast timing signals to encode the time- and position-of-arrival of multiple photofragments. The detector was demonstrated to record all three particles produced in a single three-body dissociation event, yielding an energy resolution of (approximate)15% ΔE/E at 0.7 eV in experiments on the three-body dissociative photodetachment of O6−. © 1999 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 109 (1998), S. 9215-9218 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Measurement of the translational energy partitioning in the three-body dissociative photodetachment of O6− (O6−+hν→O2+O2+O2+e−) at 532 nm is reported. Using photoelectron and photofragment translational energy spectroscopies in coincidence, a complete kinematic measurement of the three-body dissociation of neutral O6 is obtained. Vibrationally resolved product translational energy distributions are observed. The results provide insights into the structure, binding energy, and dissociation dynamics of O6− and O6 and illustrate a new approach to the study of three-body reaction dynamics. © 1998 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 103 (1995), S. 9876-9879 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Photoelectron–neutral–neutral coincidence spectra have been measured for the dissociative photodetachment of O4− (O4−+hν→O2+O2+e−) at 523 and 349 nm. The neutral photofragment translational energy spectrum, the photoelectron spectrum, and the correlations of the translational energy and photoelectron energy are presented here. The correlation spectra reveal phenomena that are not discernable in either one-dimensional measurement. Features are observed which indicate that non-Franck–Condon processes play a role in the dissociative photodetachment of O4− at 349 nm. © 1995 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 105 (1996), S. 10803-10811 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: An investigation of the photodissociation dynamics of the dimer anion O−4 at 523.6, 349.0, and 261.8 nm is reported. Product translational energy and angular distributions have been obtained using photofragment translational spectroscopy in a fast ion beam. At all wavelengths photodissociation (O−4+hν→O2+O−2) is observed to proceed via a rapid parallel electronic transition, with the photofragment angular distribution strongly peaked along the laser electric vector. The lowest energy photodissociation channel produces O2(a1Δg) and ground state O−2(X2Πg), indicating that O−4 is a doublet anion. The partitioning of energy in the dissociation reveals a complicated wavelength dependence. © 1996 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 66 (1995), S. 5507-5511 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: A high-collection-efficiency fast-ion-beam photoelectron spectrometer is described. In a straight time-of-flight mode, the spectrometer collects ∼1% of the photoelectrons and achieves an energy resolution of ΔE/E of ∼5%. For coincidence experiments requiring greater collection efficiency, a paraboloidal electrostatic mirror is used. The mirror collects ∼40% of the photoelectrons while maintaining ΔE/E≤35%. In both modes of operation, a time- and position-sensitive electron detector allows conversion of the photoelectron laboratory energy to center-of-mass energy. The fast-ion-beam photoelectron spectrometer is used to prepare mass- and energy-selected neutral molecules which are used in molecular dissociation studies. © 1995 American Institute of Physics.
    Type of Medium: Electronic Resource
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