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  • 1
    ISSN: 1432-1866
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Tourmaline alteration and high boron contents are typical features of the magmatic-hydrothermal systems of the Bolivian tin province. The average boron content in melt inclusions of quartz phenocrysts from tin porphyry systems is 225 ppm (1σ-variation range: 110–420 ppm; n=12) and suggests a magmatic boron input to the hydrothermal tin systems, and not shallow post-magmatic leaching of boron from pelitic country rocks. Boron data from melt inclusions correlate positively with cesium, rubidium and arsenic, and negatively with lithium, titanium and zirconium, and define magmatic fractionation trends. The generally high B, As, Cs and Li contents in melt inclusions suggest involvement of pelitic source lithologies undepleted in these fluid-mobile components, i.e. first-cycle metamorphic rocks. Magmatic fractionation modified the trace-element contents within a one-log-unit range. Bulk-rock Nd isotope data (ɛNd−5 to −10) are in agreement with the dominantly intracrustal geochemical signature of the Bolivian tin porphyry systems, but also imply a variable but minor mantle input. The metallogeny of the tin belt is likely a consequence of intracrustal melting of Lower Paleozoic pelitic and slightly carbonaceous source material, combined with an extended magmatic evolution. The long-lived thermal preparation of the root zones of the silicic systems is provided by mafic magma which also leaves a chemical imprint in the form of the hybrid dacitic bulk composition of the tin porphyry systems.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Mineralium deposita 29 (1994), S. 399-403 
    ISSN: 1432-1866
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Aqueous solutions with about 10 ppt195Au and [HCl] of 10−2.3 and 10−1.3 m were exposed to solid minerals for several months. The gold uptake with time was observed by time-stepped sampling and radiochemical Au analysis. Sorbants were polished thick sections of quartz, pyrite, pyrrhotite and elemental gold, as well as crushed grains and sawed mineral cubes of quartz and pyrite (all randomly oriented). The kinetics of gold sorption strongly varied with the surface area of the sorbents, the type of mineral and the pH of the solution. Mineral-specific differences in reaction rates were observed only at experimental pH values around 2.3, where sorption on pyrrhotite and elemental gold was much more rapid than by quartz and pyrite. At pH around 1.3 gold sorption was rapid on all minerals. This finding is thought to reflect the gold speciation, i.e. neutral hydroxo-gold complexes above pH 1.5, for which only chemisorption is possible, versus dominantly AuCl 4 − below pH 1.5, where unspecific electrostatic interaction enhances reaction rates with all protonated mineral surfaces.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Mineralium deposita 34 (1999), S. 241-249 
    ISSN: 1432-1866
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract The East Uralian Zone south of Cheljabinsk consists of a Silurian to Early Carboniferous volcanosedimentary sequence on Proterozoic basement, intruded by postorogenic Permian granitic rocks. The 7 by 1–2 km Bereznjakovskoje gold trend is hosted by dacitic to andesitic volcanic-subvolcanic units of Late Devonian age. Epithermal gold mineralization is of the sulfide-rich low-sulfidation (adularia-sericite) type with the metal spectrum of Au-Ag-As-Sb-Cu-Zn-Pb and a characteristic Te component. Silicic and sericitic alteration overprints barren propylitic pyrite-rich assemblages in stockworks and shear zones. Precious-metal mineralization is related to a fahlore-telluride stage overprinting earlier pyrite. Late stage redistribution and weathering liberates gold from telluride mineral phases with fixation of native gold (high fineness) on vugs and grain boundaries, and in intergrowth aggregates with supergene jarosite/limonite. Epithermal mineralization formed below the boiling level and is possibly related to a porphyry system at depth.
    Type of Medium: Electronic Resource
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