ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
We have identified an optically enhanced magnetic phase transition in the newly synthesized organic molecular charge transfer salt, (BEDT–TTF)3Ta2F11 (BEDT–TTF 3/4 bis-ethylenedithiolotetrathiafulvalene) by ESR absorption measurements in the X band microwave region. At room temperature, only a doublet state ESR absorption is observed, but below 30 K several triplet ESR absorptions appear. The orientation dependence of the ESR absorption under illumination at energies near the band gaps in the material (640 nm, T=12 to 5 K, H0〈0.34 T) indicates that there are rapid spin exchange processes with times τe〈10−8 s near 7 to 5 K along certain crystallographic directions with a temperature dependence suggesting spin-lattice relaxation times which proceed via Van Vleck "direct processes.'' This, to our knowledge, is the first case where the magnetic properties of a charge transfer salt are altered by the interaction with photons of energy equal to the band gaps in a low dimensional solid, providing a new, interesting way to investigate these materials.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.452178
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