ISSN:
1573-1111
Keywords:
Hofmann-type clathrate
;
pyrrole
;
benzene
;
aniline
;
substituted benzene
;
substituted aniline
;
1,4-diaminobutane
;
1,5-diaminopentane
;
1,6-diaminohexane
;
1,7-diaminoheptane
;
1,8-diaminooctane
;
cadmium tetracyanonickelate
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Inclusion compounds with the general formula Cd(NH2(CH2) n NH2)Ni(CN)4·xG were prepared forn=4 to 8, and for G of such an aromatic guest molecule as pyrrole, benzene, aniline, toluene, toluidine, xylene, xylidine, dichlorobenzene, trimethylbenzene, tetramethylbenzene, ethylbenzene, styrene, or isopropylbenzene, with varyingx. Generally, longer chain lengths of α,ω-diamine in the host permit the inclusion of bulkier guest molecules. However, the presence of an amino group on the phenyl ring of the guest appears to impart a special affinity with the hosts.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00665479
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