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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Journal of the American Chemical Society 114 (1992), S. 3207-3210 
    ISSN: 1520-5126
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 88 (1988), S. 524-532 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: A new experimental procedure for conducting reactive laser vaporizations is described and applied to the generation of the previously unreported copper radicals, 13CH3CuF, 12CH3CuF, HCuF, and DCuF, for rare gas matrix ESR investigations. Laser vaporization was conducted on a thin film of reactant condensed on the copper metal surface. The g and A tensors for these are compared with other small copper radicals in order to determine electronic structure and bonding trends. The neon magnetic parameters (MHz) for 13CH363CuF are: g(parallel) =1.965(1), g⊥ =2.3626(3); A(parallel)(63Cu) =3076(2), A⊥(63Cu) =2993(1); A(parallel)(19F) =94(1), A⊥(19F) =68(1); A(parallel)(13C) =19(1), A⊥(13C) 〈3. The H quartet hfs for CH3CuF was resolved on the perpendicular transitions, having an A value of 9.3(3) MHz. For H63CuF, the neon results (MHz) are: g(parallel) =1.975(1); g⊥ =2.4075(4); A(parallel)(63Cu) =2826(3), A⊥(63Cu) =2717(1); A(parallel)(19F) =127(2), A⊥(19F) =94(1); A(parallel)(H) =61(3), and A⊥(H) =29(1) MHz.
    Type of Medium: Electronic Resource
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  • 3
    facet.materialart.
    Unknown
    Paris : Periodicals Archive Online (PAO)
    Revue de littérature comparée. 44:4 (1970:oct./déc.) 540 
    ISSN: 0035-1466
    Topics: Linguistics and Literary Studies
    Notes: Notes et Documents
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Mineralogy and petrology 37 (1987), S. 293-313 
    ISSN: 1438-1168
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Description / Table of Contents: Zusammenfassung Die Nickel-Kupfer Vererzung befindet sich im Kontaktbereich einer Dioritintrusion mit hornfelsdurchdrungenen silurischen und ordovizischen Grauwacken. Die am häufigsten auftretenden Erzmineralien sind Nickelin, Gersdorffit, Pyrrhotin, Pentlandit, und Chalcopyrit mit kleineren Mengen von Molybdenit, Tellurwismuth, Gold, Sphalerit und Argentopentlandit. Weiters treten als spätere Umwandlungsprodukte Pyrit, Markasit, Violarit und Goethit auf. Ein großer Teil der Pyrrhotin-reichen Vererzung am Fuße des eingedrungenen Diorits bildet fleckige, lückenfüllende Aggregate zwischen den Silikatphasen (Amphibol, Plagioklas, Biotit, Chlorit, Quarz). Die Chalcopyrit- und Nickelin-Gersdorffit-reiche Vererzung tritt zwischen dem unvererzten Diorit im Hangenden und der Pyrrhotin-reichen Vererzung im Liegenden als linsige, lappenartige Konzentration und entlang von Fugen und Brücken auf. Vollgesteins-Analysen sowie ausgewählte Erzanalysen und Mikrosondenergebnisse der Silikate, Sulfide und Sulfarsenide liegen vor. Im Unterschied zu den typischen Dioriten zeigt der unvererzte Diorit einen niedrigen SiO2 und hohen MgO Gehalt und relativ hohe Cr, Ni und Ti Spurenelementwerte. Die Platingruppenelemente sind in den Pyrrhotin- und Chalcopyrit-reichen Vererzungen nur schwach vertreten, jedoch sind Pt, Pd und An in der Gersdorffit-reichen Vererzung stark angereichert. Ein magmatischer Ursprung dieser Vererzung, im Gegensatz zu einer metasomatischen Entstehung oder Bildung aus hydrothermalen Lösungen wird vermutet.
    Notes: Summary Nickel-copper mineralization occurs near the base of a diorite intrusion close to its contact with hornfelsed Ordovician and Silurian shales and greywackes. The principal ore minerals are nickeline, gersdorffite, pyrrhotine, pentlandite and chalcopyrite with minor amounts of molybdenite, tellurobismutite, gold, sphalerite and argentopentlandite. Pyrite, marcasite, violarite and goethite also occur but are interpreted as later alteration products. Much of the pyrrhotine-rich mineralization at the base of the intrusion is in the form of blebs and interstitial aggregates with amphiboles, plagioclase feldspar, biotite, chlorite and quartz. Chalcopyrite-rich and nickeline-gersdorffite-rich mineralization occurs above this and immediately below unmineralized diorite in the form of patches, lenticular masses and stringers along joints and fractures. Whole rock and ore analyses and electron microprobe data on the silicates, sulphides and sulpharsenides are presented. The unmineralized diorite has low SiO2 and high MgO contents compared to typical diorites and relatively high Cr, Ni and Ti trace element values. In the mineralized diorite, platinum-group elements occur in very low concentrations in the pyrrhotineand chalcopyrite-rich assemblages but Pt, Pd and Au show significant enrichment in the nickeline-gersdorffite-rich mineralization. A magmatic origin for the mineralization is proposed rather than formation by hydrothermal solutions or metasomatism.
    Type of Medium: Electronic Resource
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