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  • 1
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Materials science forum Vol. 519-521 (July 2006), p. 705-710 
    ISSN: 1662-9752
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The influence of microstructure on the electrochemical properties of an Al-5 wt% Cu binary alloywhich was severely deformed by equal-channel angular pressing (ECAP) has been investigated in aborate-boric acid buffer solution containing Cl¯ ions at pH 8.3 and 25°C by potentiodynamic polarization test.The anodic polarization results showed that pitting potentials of ECAPed Al-Cu alloy samples were higherthan that of the sample without ECAP and increased with repetitive ECAP passes. The pitting corrosionattack of Al-Cu alloy samples took place in the surroundings of Al2Cu (θ) phase. It is considered that thegrain refinement of θ phase and the solid solution generated in Al matrix during ECAP process areresponsible for the improvement of the corrosion resistance of ECAPed Al-Cu alloy
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Materials science forum Vol. 539-543 (Mar. 2007), p. 114-118 
    ISSN: 1662-9752
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Nitrogen evolution research has been widely carried out in Japan after the ForthInternational Conference on High Nitrogen Steels held in 1995 in Kyoto (HNS1995). The firstresearch forum on nitrogen evolution research has been started in The Japan Society of CorrosionEngineering in 1996, followed by a series of research forums in the Iron and Steel Institute of Japan(ISIJ). In the meantime, a pressurized electro-slag remelting furnace was newly developed inNational Institute for Material Science in 1998. A new research group regarding the availabilityof nitrogen on the improvement in steel properties has been started in ISIJ in 2004. Currentresearch activities of the group cover the fabrication of HNS such as mechanical alloying,pressurized ESR and nitrogen absorption, evaluation technologies of HNS such as microstructureand precipitation behavior of nitride, mechanical properties, corrosion properties and physicalproperties, joining/welding technologies. As one of the applications of HNS, Ni-free high nitrogensteels with high strength, anti-corrosion, non-magnetic properties are very attractive in the fields ofbio/medical ones as anti-Ni allergy material. Recent research activities including some topicsmentioned above will be discussed
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Materials science forum Vol. 539-543 (Mar. 2007), p. 2892-2897 
    ISSN: 1662-9752
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: In this study, an Al-7 wt% Si-1.5 wt% Cu alloy was subjected to severe plasticdeformation (SPD) by an equal-channel angular pressing (ECAP) technique. The ECAP processwas repetitively carried out up to 8 passes using a strain introduction method of route BC, at atemperature of 25 °C and a pressing rate of 0.33 mm s-1. Microstructures of the samples beforeand after ECAP were observed by a scanning electron microscopy (SEM). Electrochemicalproperties of the Al-Si-Cu alloy fabricated by ECAP have been investigated in a borate-boric acidbuffer solution containing Cl¯ ions at pH 8.3 and 25 °C by potentiodynamic polarization test.Corrosion pits on the sample surface after anodic polarization were investigated by means of SEM.The anodic polarization showed that as-cast Al-Si-Cu alloy with plate-shaped Si particles has poorresistance against pitting corrosion comparing to quenched sample without ECAP. Pittingpotentials of ECAPed Al-Si-Cu alloy samples were higher than that of the sample without ECAP.In the Al-Si-Cu alloy, the corrosion pits were found in the region of Si particles and the size of pitsformed on the ECAPed samples became smaller than that without ECAP. It is considered that theimprovement of the pitting resistance of ECAPed Al-Si-Cu alloy is due to homogenous distributionof spherical Si particles generated during ECAP process
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Materials science forum Vol. 539-543 (Mar. 2007), p. 4962-4967 
    ISSN: 1662-9752
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Large amount of nitrogen addition into an austenitic stainless steel can improve themechanical properties and corrosion resistance remarkably as far as the nitrogen is in solid solution.However, once the nitrogen precipitates as nitride, it results in deteriorations in the properties of thehigh nitrogen austenitic stain steel. During welding, a high nitrogen austenitic stainless steel isready to precipitate rapidly immense amounts of chromium nitride in the heat affected zone (HAZ),as intergranular or cellular morphologies at or from grain boundaries into grain interiors. The nitrideprecipitation reduces seriously the local mechanical properties and corrosion resistance. The presentauthors have demonstrated that a thermomechanical-processing as grain boundary engineering(GBE) inhibited intergranular chromium carbide precipitation in the HAZ of a type 304 austeniticstainless steel during welding and improved the intergranular corrosion resistance drastically. In thepresent study, the thermomechanical-processing was applied to a high nitrogen austenitic stainlesssteel containing 1 mass% nitrogen to suppress the nitride precipitation at or from grain boundariesin the HAZ during welding by GBE. GBE increases the frequency of coincidence site lattice (CSL)boundaries in the material so as to improve the intergranular properties, because of strong resistanceof CSL boundaries to intergranular deteriorations. The optimum parameters in thethermomechanical-processing brought a very high frequency of CSL boundaries in the highnitrogen austenitic stainless steel. The GBE suppressed the intergranular and cellular nitrideprecipitation in the HAZ of the high nitrogen austenitic stainless steel during welding
    Type of Medium: Electronic Resource
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