ISSN:
1434-1948
Keywords:
Pyrazolato ligands
;
Rhenium
;
Group-11 metals
;
Heterometallic complexes
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
By treating [(CO)3Re(Hpz)2(pz)] (Hpz = pyrazole) with [Cu(CH3CN)4]BF4, AgNO3, or [Au(tht)Cl] (tht = tetrahydrothiophene) in acetonitrile in the presence of Et3N, the corresponding trinuclear complexes {(CO)3Re(pz)3[M(CH3CN)]2} (1a-c) have been obtained. Treatment of complexes 1a-c with cyclohexyl isocyanide (c-C6H11NC) afforded the derivatives {(CO)3Re(pz)3[M(c-C6H11NC)]2} (2a-c). Complexes 2a-c have been characterized in solution by 1H-NMR spectroscopy and in the solid state by single-crystal X-ray diffraction analysis.
Additional Material:
4 Ill.
Type of Medium:
Electronic Resource
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