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  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 114 (2001), S. 3449-3455 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The dissociative photodetachment of O2−(H2O)n=1–6 was studied at 388 and 258 nm using photoelectron–multiple-photofragment coincidence spectroscopy. Photoelectron spectra for the series indicate a significant change in the energetics of sequential solvation beyond the fourth water of hydration. Photoelectron–photofragment kinetic energy correlation spectra were also obtained for O2−(H2O)1–2, permitting a determination of the first and second energies of hydration for O2− to be 0.85±0.05 and 0.70±0.05 eV, respectively. The correlation spectra show that the peak photofragment kinetic energy release in the dissociative photodetachment of O2−(H2O) and O2−(H2O)2 are 0.12 and 0.25 eV, respectively, independent of the photon and photoelectron kinetic energies. The molecular frame differential cross section for the three-body dissociative photodetachment: O2−(H2O)2+hν→O2+2H2O+e− is also reported. The observed partitioning of momentum is consistent with either a sequential dissociation or dissociation from a range of initial geometries. © 2001 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 70 (1999), S. 2268-2276 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: A new photoelectron–photofragment-coincidence spectrometer is described. Using a multiparticle time- and position-sensitive detector, this apparatus allows the study of dissociation processes of negative ions yielding three photofragments in coincidence with a photoelectron. The photoelectron spectrometer uses two detectors and works in time of flight mode, detecting 10% of the photoelectrons with an energy resolution of 5% at 1.3 eV as shown in studies of the photodetachment of O2−. A third detector is used for collection of multiple photofragments (up to 8) in coincidence. This multiparticle detector uses a crossed-delay-line anode and fast timing signals to encode the time- and position-of-arrival of multiple photofragments. The detector was demonstrated to record all three particles produced in a single three-body dissociation event, yielding an energy resolution of (approximate)15% ΔE/E at 0.7 eV in experiments on the three-body dissociative photodetachment of O6−. © 1999 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 109 (1998), S. 9215-9218 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Measurement of the translational energy partitioning in the three-body dissociative photodetachment of O6− (O6−+hν→O2+O2+O2+e−) at 532 nm is reported. Using photoelectron and photofragment translational energy spectroscopies in coincidence, a complete kinematic measurement of the three-body dissociation of neutral O6 is obtained. Vibrationally resolved product translational energy distributions are observed. The results provide insights into the structure, binding energy, and dissociation dynamics of O6− and O6 and illustrate a new approach to the study of three-body reaction dynamics. © 1998 American Institute of Physics.
    Type of Medium: Electronic Resource
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