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  • 1
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Key engineering materials Vol. 334-335 (Mar. 2007), p. 941-944 
    ISSN: 1013-9826
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The thin polymer composite bipolar plates (the thickness 〈 1.5 mm) for use in polymerelectrolyte membrane fuel cells (PEMFCs) containing vinyl ester resin, graphite [removed info] powder,organoclay have been fabricated by bulk molding compound (BMC) process. Organoclay preparedby ionic exchange of montmorillonite (MMT) with three different Mw of diamine intercalatingagents was used to reinforce the mechanical properties of the composite bipolar plates. Resultsindicate that the basal spacing and content of MMT varied with Mw of POP-diamines are critical indetermining the resultant mechanical properties for bipolar plates. The flexural strength and theunnotched impact strength of the plate were ca. 38 % (from 30.21 MPa to 45.66 MPa) and ca. 30 %(from 58.11 J/m to 80.21 J/m) higher than the pristine graphite plate, respectively, as the basalspacing of MMT (2 phr) was increased from 1.71 to 5.43 nm. The limiting oxygen index (L.O.I.)and the UL-94 test revealed that the bipolar plate possesses excellent flame retardant with L.O.I.higher than 50 and UL-94-V0. In addition, the electrical conductivity of the bipolar plates withdifferent MMT contents and basal spacing of MMT is higher than 100 S/cm
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Key engineering materials Vol. 334-335 (Mar. 2007), p. 945-948 
    ISSN: 1013-9826
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A novel organic–inorganic mesoporous silica functionalized with perfluoroalkylsulfonicacid groups analogous to that of Nafion® has been prepared. A condensation reaction between surfacesilanol groups of the mesoporous silicas and 1,2,2-trifluoro-2-hydroxy-1-trifluoromethylethanesulfonic acid Beta-sultone was conducted. High proton conducting sulfonated poly(ether etherketone) (sPEEK)/ functionalized mesoporous silica composite membranes were prepared throughhomogeneous dispersive mixing and solvent casting method. In the study, proton conductivity (σ) ofcomposite membrane is increased from 0.01 to 0.038 (S/cm) as the modified mesoporous silicacontent is increased from 0 to 5 wt. %. It is found that the ion exchange capacity (IEC) is increasedfrom 1.54 to 1.70 (meq/g) as the modified mesoporous silica content is increased from 0 to 5 wt. %.From morphology investigation, it is found that incorporation of modified mesoporous silica by rotaryvacuum evaporation enables the preparation of homogeneous membranes. The membranes present agood adhesion between inorganic domains which could be used for fuel cell applications
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Key engineering materials Vol. 334-335 (Mar. 2007), p. 129-132 
    ISSN: 1013-9826
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: This presentation will illustrate the history, current status and future development of compositeand FRP industry in Taiwan. This paper will present the characteristics of composites industry inTaiwan. The statistic survey of market and products of composite will be shown in details. Trendand development of FRP and Composites will be discussed. Unique products made in Taiwan willbe described by several categories. The challenge and prospective aspects of Composite Industrywill be discussed. Research and Development of Composite in Taiwan are critical to our industrywhich will be emphasized. International cooperation has been conducted which will be presented.Emphasis will be placed on the R&D of composites in Taiwan including: Basic research.Processing. Nanocomposites. “Green composites” and High-tech applications.Academia-industry cooperation will be discussed. International cooperation among academicinstitute, society/association and foreign industry will also be illustrated
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Key engineering materials Vol. 334-335 (Mar. 2007), p. 789-792 
    ISSN: 1013-9826
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The functionalized multiwall carbon nanotubes (MWNTs) have been prepared by freeradical reaction with maleic acid and maleic anhydride. The functionalized MWNT was furtherblended with poly(dimethylsiloxane) (PDMS) based Poly(urea-urethane) (PUU). Both maleic acidmodified MWNT (Maa-g-MWNT) and maleic anhydride modified MWNT (Mah-g-MWNT) showedenhanced dispersion compared with that of pristine MWNT and PUU.For MWNT/PUUnanocomposites containing 5 phr functionalized MWNT, the maximum microwave absorption was-19.2 dB for Maa-g-MWNT/PUU nanocomposites and was -22 dB for Mah-g-MWNT/PUUnanocomposites
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 1572-8935
    Keywords: Epoxy ; Blend ; Polycarbonate ; Transesterification
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract PC-DER331 blends are transparent and homogeneous due to the transesterification taking place during hot melting process. This transesterification reaction does not occur or occurs insignificantly during the preparation of PC-DER332 blends. PC is separated from the PC-DER332 melt mixture by slow cooling to room temperature but the mixture remains a single phase by quenching with an ice bath. Two systems of PC-epoxy blends, PC-DER331 blends and PC-DER332 blends are cured by the m-phenylene diamine (MPDA) in a stoichiometric ratio. Curing kinetics have been carried out by differential scanning calorimeter (DSC). The presence of PC accelerates the curing reaction. Infrared spectroscopy (IR) indicates the occurrence of transesterification in the PC-DER331/MPDA blends during curing. The flexural modulus increases with the increase of the PC content while the notched Izod impact strength decreases with the increase of the PC content for all the blending systems. The fracture surfaces of the PC-DER331/MPDA blends are smooth, an indication of a homogeneous morphology. The fracture surfaces of the PC-DER332/MPDA blends are rough, an indication of a heterogeneous morphology.
    Type of Medium: Electronic Resource
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  • 6
    ISSN: 1572-8935
    Keywords: Fatigue behavior ; C.F./PEEK ; Composites ; Weibull distribution function ; Hygrothermal ; Impact
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract The hygrothermal effects on the fatigue behavior of the Carbon/PEEK laminated composites before and after impact damage were examined in this study. The [0/45/90/-45]2s AS-4/PEEK laminated composites were immersed in 80°C hot water for 45, 90 and 200 days,and subjected to falling weight impact with an energy of 8.58 J and then immersed in 80°C hot water for 45 days. It was found that the tensile strength of AS-4/PEEK laminated composites decreased with the increase of exposure period. The injured AS-4/PEEK composites were subjected to a static load and a tensiontension fatigue load at various levels of stress amplitudes. The effect of stress amplitude on the fatigue life was studied. The experimental fatigue life under different stress amplitude tests were estimated by the median rank order statistic cumulative distribution function. Then,the fitting curves for estimated data were analyzed by the Weibull distribution function. The S-N curves for a series of cyclic loads at various survival probabilities were presented. The damage behaviors of composites after fatigue load test were also investigated by scanning electron microscope(SEM). Results indicated the fatigue lives of immersed specimens were shorter than those without hygrothermal effect, the impact damage affects the fatigue life of composite significantly.
    Type of Medium: Electronic Resource
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  • 7
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The effects of processing parameters on the microstructure and oxidation resistance of silicon carbide (SiC) coated carbon-carbon (C-C) composites were investigated. C-C composites were made from plain woven carbon cloths and phenolic derived carbon matrices in the laboratory. Pressureless reaction sintering has been used to apply SiC coating to C-C composites using epoxy resin and silicon powder as the precursor. Results showed that the oxidation resistance of C-C composites was enhanced by coating with SiC. The pressureless reaction sintering process exhibits good processability. β-SiC was formed after heat treatment at 1800 °C and the α-SiC formed after heat treatment at 2200 °C. The SiC coated C-C composites exhibit good oxidation resistance at 1000 °C for 100 h under the test conditions.
    Type of Medium: Electronic Resource
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  • 8
    ISSN: 1573-4811
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 30 (1995), S. 1225-1232 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The dynamic mechanical analysis (DMA) method was utilized to investigate the dynamic mechanical properties of the carbon-phenolic composite, and of carbon-carbon (C/C) composites carbonized at 1000°C, and graphitized at 2200°C. The measurements were performed in the temperature range 50–450°C. Results show that the carbon-phenolic composite has the highest storage modulus, while the carbonized C/C composites possess higher storage modulus than the graphitized C/C composite. The storage moduli of carbonized and graphitized C/C composite do not change significantly in the test temperature range. The tan δ, loss factor, of carbonized C/C composites increases 59.5% during the tests from 50 to 450°C, and that of the graphitized C/C decreases 9.74% in the same temperature range; graphitized C/C shows the highest tan δ at 50 °C. The carbon-phenolic composite shows a damping peak at 250 °C, which is probably due to the transition from glassy state to rubbery state of the phenolic matrix. The higher tan δ of the graphitized C/C composite may be due to matrix graphitization, fibre-matrix debonding and crack formation, which were observed on the micrographs.
    Type of Medium: Electronic Resource
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  • 10
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The influence of the fabrication parameters during carbonization and densification processes on the mechanical properties and the microstructure of carbon/carbon (C/C) composites were investigated. The C/C composites were made by using phenolic resin as precursor and two-dimensional carbon fabrics as reinforcements for the first carbonization. The effects of heating rate and heat-treatment temperature during the initial carbonization process on the properties of C/C composites are presented. Further densification treatment was completed by chemical vapour infiltration (CVI) and a liquid-resin impregnation process. The CVI route was found to be more efficient than the resin-impregnation process. The interlayer spacing of C/C composites did not change after resin re-impregnation for several times. However, the interlayer spacing of the C/C composites was reduced when the processing temperature in the CVI process was increased. Higher flexural strength and flexural modulus were obtained because the densities of the composites were enhanced either by the chemical vapour infiltration process or by the resin-impregnation route. The variation in thickness of the CVI deposited carbon within the preformed composite was studied and the morphology of the fracture surface of the C/C composites was also examined.
    Type of Medium: Electronic Resource
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