ISSN:
0377-0486
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
A simple, small-volume, low-temperature bulk electrolysis Raman spectroelectrochemical cell has been constructed which allows collection of resonance Raman (RR) spectra in situ from a rapidly stirred electrolysed solution. The cell has been used to obtain the first RR spectrum of electrochemically generated ferryl tetramesitylporphyrin (TMPFeIV =O), formed at -40°C by electrooxidation of TMPFeIIIOH in CH2CI2 solution.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jrs.1250190810
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