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  • 1
    Electronic Resource
    Electronic Resource
    The Polymerization of Metal-Containing Vinylic Monomers of Iron and Tungsten with Metal–Carbon σ Bonds (1997)
    Springer
    Journal of inorganic and organometallic polymers and materials 7 (1997), S. 233-250 
    Details
    ISSN: 1572-8870
    Keywords: Metal-containing vinylic monomers ; organometallic polymers ; free-radical polymerization
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract A series of metal-containing vinylic monomers of the type $${\text{L}}_n {\text{MCOC}}_6 {\text{H}}_4 {\text{CH = CH}}_2 $$ and $${\text{L}}_n {\text{MCOCH = CHC}}_{\text{6}} {\text{H}}_5 [{\text{L}}_n {\text{M = (}}\eta ^{\text{5}} {\text{ - C}}_{\text{5}} {\text{H}}_{\text{5}} {\text{Fe(CO)}}_{\text{2}} {\text{),(}}\eta ^{\text{5}} {\text{ - C}}_{\text{5}} {\text{Me}}_{\text{5}} {\text{)Fe(CO)}}_{\text{2}} ),{\text{(}}\eta ^{\text{5}} {\text{ - C}}_{\text{5}} {\text{H}}_{\text{5}} {\text{W(CO)}}_{\text{3}} )]$$ was homopolymerized using 2,2′-azobisisobutyronitrile (AIBN) as the free-radical initiator. These monomers were also copolymerized with styrene in the presence of AIBN. These compounds represent a class of organometallic polymers in which the metal is bonded to the polymer backbone via a metal–carbon σ bond. The new compounds were characterized by IR and 1H NMR spectroscopy as well as scanning electron microscopy, gel permeation chromatography, and thermoanalytical studies (DSC and TGA). The properties of the new organometallic polymers are discussed.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1021694624452
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  • 2
    Electronic Resource
    Electronic Resource
    The synthesis and characterization of metal-containing vinylic monomers of iron and tungsten (1998)
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 12 (1998), S. 801-807 
    Details
    ISSN: 0268-2605
    Keywords: metal-containing vinylic monomers ; vinylbenzoyl complexes ; cinnamoyl complexes ; tungsten-olefin monomers ; iron-olefin monomers ; Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A series of metal-containing vinylic monomers of the type LnM(COC6H4CH=CH2) and LnM (COCH=CHC6H5) [LnM = (η5-C5H5)Fe(CO)2, (η5-C5Me5)Fe(CO)2 and (η5-C5H5)W(CO)3] were prepared by the reaction of the appropriate metal anion with either 4-vinylbenzoyl chloride or cinnamoyl chloride. (η5-C5H5)(CO)2FeCOCH=CH2 was prepared by the reaction of Na[(η5-C5H5)Fe(CO)2] and acryloyl chloride, whereas the compound (η5-C5H5)(CO)2Fe(C6H4CH=CH2) was prepared via a transmetallation reaction using a palladium catalyst. All compounds were fully characterized using FTIR, 1H and 13C NMR spectroscopy and mass spectrometry. Copyright © 1998 John Wiley & Sons, Ltd.
    Additional Material: 5 Tab.
    Type of Medium: Electronic Resource
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    Paper (German National Licenses)
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