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  • 1
    ISSN: 1432-0819
    Keywords: Key words Fluid geochemistry ; Thermal springs ; Fumaroles ; Guadeloupe ; Geothermal ; Volcano
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract  The purpose of this work was to study jointly the volcanic-hydrothermal system of the high-risk volcano La Soufrière, in the southern part of Basse-Terre, and the geothermal area of Bouillante, on its western coast, to derive an all-embracing and coherent conceptual geochemical model that provides the necessary basis for adequate volcanic surveillance and further geothermal exploration. The active andesitic dome of La Soufrière has erupted eight times since 1660, most recently in 1976–1977. All these historic eruptions have been phreatic. High-salinity, Na–Cl geothermal liquids circulate in the Bouillante geothermal reservoir, at temperatures close to 250  °C. These Na–Cl solutions rise toward the surface, undergo boiling and mixing with groundwater and/or seawater, and feed most Na–Cl thermal springs in the central Bouillante area. The Na–Cl thermal springs are surrounded by Na–HCO3 thermal springs and by the Na–Cl thermal spring of Anse à la Barque (a groundwater slightly mixed with seawater), which are all heated through conductive transfer. The two main fumarolic fields of La Soufrière area discharge vapors formed through boiling of hydrothermal aqueous solutions at temperatures of 190–215  °C below the "Ty" fault area and close to 260  °C below the dome summit. The boiling liquid producing the vapors of the Ty fault area has δD and δ18O values relatively similar to those of the Na–Cl liquids of the Bouillante geothermal reservoir, whereas the liquid originating the vapors of the summit fumaroles is strongly enriched in 18O, due to input of magmatic fluids from below. This process is also responsible for the paucity of CH4 in the fumaroles. The thermal features around La Soufrière dome include: (a) Ca–SO4 springs, produced through absorption of hydrothermal vapors in shallow groundwaters; (b) conductively heated, Ca–Na–HCO3 springs; and (c) two Ca–Na–Cl springs produced through mixing of shallow Ca–SO4 waters and deep Na–Cl hydrothermal liquids. The geographical distribution of the different thermal features of La Soufrière area indicates the presence of: (a) a central zone dominated by the ascent of steam, which either discharges at the surface in the fumarolic fields or is absorbed in shallow groundwaters; and (b) an outer zone, where the shallow groundwaters are heated through conduction or addition of Na–Cl liquids coming from hydrothermal aquifer(s).
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Industrial and engineering chemistry 24 (1985), S. 296-301 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1432-0819
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Three points raised in the paper by Tedesco and Sabroux (1987) are dealt with. (1) The inconsistency between the water partial pressure calculated by Tedesco and Sabroux (1987) and saturation pressure is due to the improper use of the water-gas-shift reaction as a geothermometer. In fact Tedesco and Sabroux (1987) do not take into account the distribution of gas species between the coexisting vapour and liquid phases. (2) The depth of the “steam reservoir” is evaluated by Tedesco and Sabroux (1987) in too simplistic a way. This matter should be treated with greater care owing to the high social impact of any consideration on the Phlegraean Fields system. (3) The reliability of carbon monoxide determination at the concentration level encountered at Solfatara depends on the collection method rather than on the gas-chromatographic technique.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 1432-0819
    Keywords: Key words Fumaroles ; Fluid chemistry ; δD value ; δ18O value ; Volcanic surveillance ; Vulcano Island
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract  Variations in δD and δ18O values with H2O contents and outlet temperatures indicate that the fumaroles of La Fossa crater have discharged mixtures of magmatic water and marine hydrothermal water, since 1979. The contribution of meteoric water was low in the period 1979–1982 and very low afterwards. The δ18O values of the marine-hydrothermal component of +5 to +7.2ö are due to isotopic exchange with the 18O-rich silicates of the rocks under high-temperature and low-permeability conditions. The δ18O value of the magmatic end-member is generally +3.5 to +4.3ö, although values as high as +5.5 to +6.5ö were reached in the summer of 1988, when magma degassing appears to have extended into the core of the magma body. The δD values of the end-member were close to –20ö, typical of andesitic waters. Both the isotopic values and chemical data strongly support a 'dry' model, consisting of a central magmatic gas column and a surrounding hydrothermal envelope, in which marine hydrothermal brines move along limited fracture zones to undergo total evaporation on approaching the conduits of magmatic fluids.The vents at the eastern and western boundaries of the fumarolic field are fed by fluids whose pressure is governed by the coexistence of vapor, liquid and halite, giving rise to a high risk of phreato magmatic explosions, should magma penetrate into these wet environments. Most La Fossa eruptions were triggered by an initial hydrothermal blast and continued with a series of phreatomagmatic explosions.The fluids discharged by the Forgia Vecchia fumaroles are mixed with meteoric water, which is largely evaporated, although subordinate loss of condensed steam may be responsible for scrubbing most of the acidic gas species. The temperatures and pressures, and the risk of a sudden pressure increase, are low.A boiling hydrothermal aquifer at 230°  C is present underneath the Baia di Levante beach. This area has a minor risk of hydrothermal explosions.
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 1432-0819
    Keywords: Key words Sulfur isotopes ; Magma degassing ; Somma-Vesuvius volcanic complex
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Sulfur contents and δ34S values of Somma-Vesuvius magmas are consistent with syneruptive, open-system degassing at temperatures of 800–850°C for Plinian pumices and 1100–1200°C for lavas. The extent of degassing appears to be greater in lavas than in pumices. The key parameter controlling the 34S/32S ratio of Somma-Vesuvius volcanics is the average magma oxidation state, which generally varies from 0.85 to 1.20 Δ NNO units for lavas and from 1.20 to 1.40 Δ NNO units for pumices. Consequently, S contents and δ34S values of magmas constitute a potentially valuable tool in estimating their average redox conditions. The results of this study may help in risk mitigation when the Vesuvius magmatic system evolves toward eruptive conditions.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 30 (1984), S. 401-408 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: By the use of a perfectly mixed model and an imperfectly mixed one for lowdensity polyethylene vessel reactors, we show that increases in the initiator consumption with polymerization temperature are due to mixing limitations at the initiator feed. With all its parameters independently estimated, the imperfectly mixed model provides an excellent agreement with experimental data for several initiators, feed flow rates and polymerization pressures. In the temperature region of industrial interest for each type of initiator, the open-loop reactor dynamics drastically change from open-loop unstable, at low temperatures, to open-loop stable at high polymerization temperatures.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 30 (1984), S. 409-415 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: By the use of an imperfectly mixed model developed for LDPE vessel reactors, we show that a linear controller cannot perform satisfactorily in the entire range of operating conditions of industrial interest. Based on the concept of reaction rate control, a novel controller is developed which provides satisfactory closed-loop dynamics independent of steady-state conditions. A nonlinear controller is shown to be more effective in avoiding reactor light-off.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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