Electronic Resource
College Park, Md.
:
American Institute of Physics (AIP)
The Journal of Chemical Physics
100 (1994), S. 6778-6782
ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
A reversible adsorption–desorption parking process in one dimension is studied. An exact solution for the equilibrium properties is obtained. The coverage near saturation depends logarithmically on the ratio between the adsorption rate, k+, and the desorption rate, k−, ρeq(approximately-equal-to)1−1/log(k+/k−), when k+/k−(very-much-greater-than)1. A time dependent version of the reversible problem with immediate adsorption (k+=∞) is also considered. Both heuristic arguments and numerical simulations reveal a logarithmically slow approach to the completely covered state, 1−ρ(t)∼1/log(t).
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.467037
Permalink
Library |
Location |
Call Number |
Volume/Issue/Year |
Availability |