ISSN:
0001-1541
Keywords:
Chemistry
;
Chemical Engineering
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Process Engineering, Biotechnology, Nutrition Technology
Notes:
Hydrogen sulfide is oxidized to elemental sulfur by ferric ion chelated with nitrilotriacetic acid (NTA) in aqueous solution at pH 3.5 to 4.5. The reaction appears to be fast relative to gas- and liquid-phase diffusion, and the transfer of H2S from a gas stream is correlated well by the theory of absorption with instantaneous chemical reaction. The ferrous ion formed in this reaction may be reoxidized with oxygen absorbed from a stream of air. The presence of NTA catalyzes the reaction of O2 and Fe2+ in the same pH range, and diffusion is again controlling. Design calculations based on laboratory data for both absorption steps show that cocurrent gas-liquid contactors are advantageous for achieving high reaction rates (e.g., ∼99.99% H2S removal), high gas velocities (10 to 20 m/s), low pressure drops [1 to 3 kPa (10 to 30 cm H2O)], and moderate column heights (10 to 15 m).
Additional Material:
4 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/aic.690300111
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