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  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 988-994 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The extent of high temperature (900-1,300°C), short time (〈1 s) SO2 capture was found to be limited by temperature-dependent losses in the porosity of calcium based sorbents. At 970°C these porosity losses were caused by CO2-activated sintering. Sulfation of the sorbents either prevented or reduced the extent of porosity losses. Differences in SO2 capture between hydroxides from different commercial sources, and significantly lower levels of capture by calcium carbonates compared to hydroxides were attributed to differences in particle size and the degree of porosity loss.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 36 (1990), S. 1865-1872 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A model of the reaction between SO2 and calcium-based slurries is presented. The model is coupled with an extensive model of the evaporation process and considers external SO2 mass transfer and liquid-phase mass transfer of dissolved sulfur and calcium species in both the film surrounding the calcium particles and the bulk liquid phase. The model assumes that particles do not circulate within slurry droplets and that evaporation results in an accumulation of particles at the droplet surface that causes a shift in the controlling mechanisms. Agreement between the model and data available in the literature is excellent.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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