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  • 1
    Electronic Resource
    Electronic Resource
    Palo Alto, Calif. : Annual Reviews
    Annual Review of Materials Research 20 (1990), S. 299-338 
    ISSN: 0084-6600
    Source: Annual Reviews Electronic Back Volume Collection 1932-2001ff
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Oxidation of metals 21 (1984), S. 285-297 
    ISSN: 1573-4889
    Keywords: Galvalume ; elevated temperature ; intermetallic formation ; Al13Fe4 ; oxidation ; vaporization
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Galvalume (trademark of Bethlehem Steel Corp.) sheet steel samples were heated in pure oxygen and 97% O2/3% H2O atmospheres at temperatures ranging from 300 to 670°C. Time at a particular temperature was varied but did not exceed 48 hr. Above 480°C, the Galvalume coating became rapidly alloyed with iron to form Al13Fe4, and zinc was lost by vaporization. The Zn content dropped to about 15 wt%. The time required to fully alloy the overlay at 490°C was less than 4 hr. Below 480°C, only minor microstructural changes occurred, and coating integrity was maintained. No differences in behavior were observed by the addition of 3% water vapor to the gas stream.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Journal of applied electrochemistry 11 (1981), S. 453-461 
    ISSN: 1572-8838
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract The transport processes occurring within the diffusion layer of dissolving anodes are analysed with the help of a mathematical model which takes into account mass transfer by both diffusion and ionic migration in the presence of a supporting electrolyte. The steady-state transport equations are solved for the ionic concentrations and potential difference as a function of distance within the diffusion layer, metal-ion charge and diffusivity, supporting electrolyte concentration and metal dissolution rate. Upon normalization of the variables, a dimensionless group $$(I = ix/zFc^0 D_{M^{z + } } )$$ is obtained. This group includes the transport properties of the system and shows the inter-relationship between them. The anodic dissolution of Cu in HClO4 was chosen to test some of the predictions of the system. The measured metalion concentrations were much less, while the potential gradient was much higher, than predicted. This is explained on the basis of ionic interactions which operate at higher concentrations. It is shown, both theoretically and experimentally, that in this strong acid medium the concentration of hydrogen ions decreases in the diffusion layer of a dissolving anode due to ionic migration of the hydrogen ions in accord with the prevailing potential gradient.
    Type of Medium: Electronic Resource
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