ISSN:
1434-1948
Keywords:
Phosphane ligands
;
31P-NMR spectrometry
;
Substituent increments
;
Electronic and steric properties
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The syntheses and spectroscopic parameters of the new tertiary phosphane ligands (p-MeOC6H4)(o-MeOC6H4)2P (1), (p-MeOC6H4)(o-MeSC6H4)2P (2), (p-MeSC6H4)(o-MeSC6H4)2P (3), (p-MeSC6H4)(o-MeOC6H4)2P (4), (p-MeOC6H4)(o-NC5H4)2P (5), and (p-MeSC6H4)(o-NC5H4)2P (6) are reported. Single-crystal X-ray structures of all the compounds (1-6) have been determined. The dependence of the 31P-NMR chemical shifts on the substituent groups of the phosphanes is discussed.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
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