ISSN:
0025-116X
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
The doping of deuterated polyacetylene (cis and trans) with AsF5 was studied by neutron diffractometry. A method of optimize the crystallinity of the doped material is described. Evidence for the presence of two species in the doped polymer which are probably AsF6- and AsF3 is presented. Model calculations based on a series of [CDxH1-x(AsF5)y]n samples support a “first-stage” intercalation structure with a graphitic structure.
Additional Material:
21 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/macp.1984.021850216
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