ISSN:
1432-0827
Keywords:
Key words: Human tooth enamel — EPR spectrum — ENDOR spectrum.
Source:
Springer Online Journal Archives 1860-2000
Topics:
Biology
,
Medicine
,
Physics
Notes:
Abstract. Powdered tooth enamel heated at 400°C has been examined with electron paramagnetic resonance (EPR), electron-nuclear double resonance (ENDOR), and ENDOR-induced EPR (EIEPR) methods and compared with hydroxyapatite synthesized at high temperature. The EPR spectrum of the tooth enamel sample consists mainly of signals assigned to O− and CO2 − radicals, in contradistinction to the synthetic apatite sample, where signals of O− and CO3 3− were detected. The ENDOR results of heated enamel show that the O− radical is located at an A site and interacts with three unequivalent sets of 31P nuclei and two unequivalent protons. This supports the model proposed for synthetic apatite. The EIEPR results show that the 31P and 1H ENDOR resonances originate from both O− and CO2 − radicals and that the 23Na and 19F resonances originate only from a CO2 − radical located probably at the surface.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/s002239900549
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