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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Chemistry of materials 7 (1995), S. 1957-1967 
    ISSN: 1520-5002
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Inc
    Journal of the American Ceramic Society 88 (2005), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: When a porous material that is saturated with liquid is heated, the liquid expands much more than the solid phase. If the permeability is low, then the liquid may not be able to escape as it expands, so it expands within the pores and causes dilatation of the body. In that case, by analyzing the kinetics of dilatation during a change in temperature, it is possible to extract the permeability. Previous papers have examined the behavior of an elastic or viscoelastic (VE) porous solid subjected to a thermal cycle slow enough to avoid internal temperature gradients. However, for cementitious samples, the sample size must be large enough that thermal gradients are likely. In this paper, we show that the effect of the gradient can be readily incorporated into the analysis of experimental data. For cement paste, experiments reveal that VE relaxation has a greater influence on the results than the gradient in temperature.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Journal of sol gel science and technology 2 (1994), S. 277-281 
    ISSN: 1573-4846
    Keywords: thermoporometry ; densification of aerogels ; PDA: Partially densified aerogels ; impregnation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The evolution of the texture of silica aerogels during sintering is studied by thermoporometry for both neutral and base catalysed materials. During the densification the macroporous volume drops and the analysis of the mesopore size distribution evolution shows that the collapse of the smallest mesopores is responsible for the macropore volume transformation. However, corrections of the measured volumes are necessary to characterize the most compliant materials.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Journal of sol gel science and technology 2 (1994), S. 507-512 
    ISSN: 1573-4846
    Keywords: KTiOPO4 ; integrated optics ; phosphates ; 31P NMR
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract A sol gel route has been developed to produce stoichiometric, dense and crack free KTiOPO4 (KTP) thin films which exhibit waveguiding. This method involved the deposition and pyrolysis of hydrolyzed solutions of K, Ti and P alkoxides on an appropriate substrate. The final ceramic film morphology is greatly dependent on the preparation chemistry, apparently as a result of the formation of polymetallic complexes. The solution chemistry, processing conditions and their influence on the final ceramic film microstructure will be discussed in detail. Optical properties such as indices of refraction and optical losses have been found to be dependent on the film microstructures. Deposition on different substrates has been undertaken to promote preferential orientation and thus to try to minimize the optical losses in the films. This correlation between the optical losses and microstructures will be discussed in detail.
    Type of Medium: Electronic Resource
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