ISSN:
0268-2605
Keywords:
dmit
;
dmio
;
metal complexes
;
cyclopentadienyl
;
cobalt(III) complex
;
cyclic voltammetry
;
controlled potential coulometry
;
electron reservoir
;
sulphur-rich organic electron donor
;
Chemistry
;
Industrial Chemistry and Chemical Engineering
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Four novel cobalt(III) complexes with a cyclopentadienyl or pentamethylcyclopentadienyl ring and dmit or dmio ligands were synthesized, and their electrochemical behaviour was investigated. All these complexes exhibited three one-electron transfer steps: one reduction and two oxidation steps. In addition, a novel organosulphur compound was afforded by electrochemical oxidation of dmit cobalt complex. Thus, these complexes may have considerable synthetic potential as precursors for electron reservoirs and organosulphur compounds.
Additional Material:
7 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/aoc.590050404
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