ISSN:
1573-1111
Keywords:
Benzo-15-crown-5
;
alkali cation
;
alkaline earth cation
;
X-ray deffraction
;
cation discrimination
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract X-ray structural results have been reviewed for the related Mz+ L z − -B15C5 complexes where Mz+=Li+ to Cs+ and Mg2+ to Ba2+, L−=2,4,6-trinitrophenolate (Picrate or Pic) and 3,5-dinitrobenzoate (Dnb), and B15C5=benzo-15-crown-5. These results combined with those for come MXz-B15C5 (X=NCS−, I−, NO 3 − , ClO 4 − , BPh 4 − ) complexes have revealed that B15C5 is a useful macrocycle with regard to the ‘within-the-group’ and ‘between-the-groups’ discriminations of Mz+ in the solid state.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00662080
Permalink