ISSN:
0009-2940
Keywords:
η4-Arene ligand
;
Hydrogen bonds, phenol
;
Palladium complexes
;
Bond activation, P—C
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Pd[P(tBu)3]2 reacts photochemically with an excess of phenol in n-hexane to give the dinuclear complex [{P(tBu)2H}2Pd2{μ-P(tBu)2}(μ-η2:η2-C6H5O)] — 3 C6H5OH (1); X-ray crystallography shows a linear chain of three phenol molecules hydrogenbonded to the phenoxide ligand which is η4-coordinated to the Pd2 framework. The π coordination of the phenoxide ring is retained in solution, as evidenced by 1H-NMR spectroscopy.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19911240117
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