ISSN:
1042-7163
Keywords:
Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Complex [Cu(SC6H2Pri 3-2,4,6)]8 (1) reacts with a small amount of CS2 to give red crystals [Cu6(S2CSC6H2Pri3-2,4,6)4(SC6H2Pri3-2,4,6)2] · 2CHCl3 · 4CH3OH (2), and CS2 is inserted into two-thirds of the Cu—S bonds of complex (1). The unusual structure of complex (2) consists of six copper atoms linked through arenethiolate (RS-) and aryl trithiocarbonate (RSCS2-) ligands, exhibiting a number of interesting features. Crystal data: triclinic, space group P1, a = 14.298(4), b = 14.282(5), c = 17.745(7)Å, α = 109.92(3), β = 111.88(3), γ = 90.42(2)°, Z = 1, R = 7.83%, for 4118 observed reflections.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hc.520030532
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