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Crystal Structure, Infrared, and Polarized Raman Spectra of K3Sm(PO4)2 (1999)

Toumi, Mohamed ; Smiri-Dogguy, Leila ; Bulou, Alain

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 1999 (1999), S. 1545-1550

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ISSN: 1434-1948

Keywords: Phosphates ; Structure ; IR spectroscopy ; Raman spectroscopy ; Chemistry ; General Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The low-temperature form of K3Sm(PO4)2 crystallizes in the monoclinic system [a = 7.4347(5) Å, b = 5.6270(5) Å, c = 9.4919(5) Å, β = 90.870(6)°, Z = 2, space group P21/m]. The structure has been determined using 1263 independent reflections (R = 0.045, Rw = 0.11) and is found to be of the glaserite type. The Raman and infrared spectra have been investigated: they are consistent with the proposed space group and an assignment of the observed frequencies is given.

Additional Material: 3 Ill.

Type of Medium: Electronic Resource

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