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  • 1
    ISSN: 1572-8838
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract 4-Ethoxytoluenes bearing substituents in the β-position such as a hydroxy group, a halogen atom, or an ester group were anodically oxidized to give the corresponding benzaldehydes or their derivatives (dimethyl acetals, hydrogen sulphite addition products). The electrochemical oxidation of 4-alkyloxytoluenes in alcoholic solutions in the presence of alkanediols led to cyclic acetals, e.g. 1,3-dioxolanes and 1,3-dioxanes. Various 2,5-disubstituted 1,3-dioxanes were thus prepared, the trans isomers exhibiting liquid-crystalline properties. The ratio of cis and trans isomers formed during the electrolysis was found to be in correspondence with the thermodynamic equilibrium.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 26 (1998), S. 485-495 
    ISSN: 0271-2091
    Keywords: capillarity ; free surface ; finite elements ; validation ; Engineering ; Numerical Methods and Modeling
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The mathematical formulation of the dynamics of free liquid surfaces including the effects of surface tension is governed by a non-linear system of elliptic differential equations. The major difficulty of getting unique closed solutions only in trivial cases is overcome by numerical methods. This paper considers transient simulations of liquid-gas menisci in vertical capillary tubes and gaps in the presence of gravity. Therefore the CFD code FIDAP 7.52 based on the Galerkin finite element method (FEM) is used. Calculations using the free surface model are presented for a variety of contact angles and cross-sections with experimental and theoretical verification. The liquid column oscillations are compared for numerical accuracy with a mechanical mathematical model, and the sensitivity with respect to the node density is investigated. The efficiency of the numerical treatment of geometric non-trivial problems is demonstrated by a prismatic capillary. Present restrictions limiting efficient transient simulations with irregularly shaped calculational domains are stated. © 1998 John Wiley & Sons, Ltd.
    Additional Material: 15 Ill.
    Type of Medium: Electronic Resource
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