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  • 1
    Electronic Resource
    Electronic Resource
    On the error of the quasi-steady-state approximation (1993)
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 97 (1993), S. 163-172 
    Details
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1021/j100103a028
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  • 2
    Electronic Resource
    Electronic Resource
    Principal component analysis for reducing the Edelson-Field-Noyes model of the Belousov-Zhabotinskii reaction (1986)
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 90 (1986), S. 1664-1670 
    Details
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1021/j100399a042
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    Paper (German National Licenses)
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  • 3
    Electronic Resource
    Electronic Resource
    KINAL-a program package for kinetic analysis of reaction mechanisms
    Amsterdam : Elsevier
    Computers and Chemistry 14 (1990), S. 253-254 
    Details
    ISSN: 0097-8485
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    URL: http://linkinghub.elsevier.com/retrieve/pii/0097-8485(90)80054-6
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  • 4
    Electronic Resource
    Electronic Resource
    Parameterization of reaction mechanisms using orthonormal polynomials
    Amsterdam : Elsevier
    Computers and Chemistry 18 (1994), S. 45-54 
    Details
    ISSN: 0097-8485
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    URL: http://linkinghub.elsevier.com/retrieve/pii/0097-8485(94)80022-7
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  • 5
    Electronic Resource
    Electronic Resource
    Kinetics of reactions occurring in the unpolluted troposphere, II. Sensitivity analysis (1990)
    Springer
    Reaction kinetics and catalysis letters 41 (1990), S. 103-108 
    Details
    ISSN: 1588-2837
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Abstract Механизм, описывающий кинетику реакций в незагрязненой тропосфере, был исследован, анализируя чувствительности на скорости и на концентрации. В результате была получена модель из 50 ступеней, которая подтверждает изменение важности отдельных реакций в течение дневного цикла.
    Notes: Abstract A reaction mechanism suggested for the description of the kinetics in the unpolluted troposphere was investigated by rate sensitivity and concentration sensitivity analyses. The study resulted in a 50-step reduced model and revealed the change of the importance of reactions during a diurnal cycle.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02075489
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  • 6
    Electronic Resource
    Electronic Resource
    Collisional energy transfer in the two-channel decomposition of 1,1,2,2-tetrafluorocyclobutane and 1-methyl-2,2,3,3-tetrafluorocyclobutane, II. Gas/wall collisions (1993)
    Springer
    Reaction kinetics and catalysis letters 51 (1993), S. 409-414 
    Details
    ISSN: 1588-2837
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The efficiency of gas/wall vibrational energy transfer has been studied over the temperature range 800–1100 K by the “variable encounter” method. The average energies transferred per deactiviting collisions with the wall were determined at 800 K to be 3200 cm−1 and 2900 cm−1 for the 1,1,2,2-tetrafluorocyclobutane (TFCB) and 1-methyl-2,2,3,3-tetrafluorocyclobutane (MTFCB) molecules, respectively. This energy increased strongly with decreasing temperature. A comparison is made of 〈ΔE′〉 with previous results for related molecules.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02069085
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  • 7
    Electronic Resource
    Electronic Resource
    Collisional energy transfer in the two-channel decomposition of 1,1,2,2-tetrafluorocyclobutane and 1-methyl-2,2,3,3-tetrafluorocyclobutane, I. Gas/gas collisons (1993)
    Springer
    Reaction kinetics and catalysis letters 51 (1993), S. 401-408 
    Details
    ISSN: 1588-2837
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The two-channel thermal decomposition of 1,1,2,2-tetrafluorocyclobutane (TFCB) and 1-methyl-2,2,3,3-tetrafluorocyclobutane (MTFCB) have been studied in the temperature range of 730–805 K at pressures varied from 1.1 Pa up to 4.6 kPa. In the pressure independent range, Arrhenius expressions were obtained for TFCB decomposition into 2 CH2CF2 (k1) and C2H4+C2F4 (k2), respectively. The same kinetic equations were determined for the decomposition of MTFCB into C3H4F2+C2H2F2 (k3) and C3H6+C2F4(k4). From the study of the pressure dependence of the homogeneous decomposition rates, the average downward energy transfer values of 1800±200 cm−1 and 1600±200 cm−1 were obtained for the TFCB and MTFCB molecules, respectively.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02069084
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  • 8
    Electronic Resource
    Electronic Resource
    Rate sensitivity analysis of a model of the Briggs-Rauscher reaction (1991)
    Springer
    Reaction kinetics and catalysis letters 45 (1991), S. 235-241 
    Details
    ISSN: 1588-2837
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Abstract Современный механизм реакции Бригса-Раушера (известной также как реакция “иодных часов”) был исследован с помощью принципиального компонентного анализа матрицы чуствительности реакции. Анализ подтверждает, что 5 реакций из 15и-ступенчатой модели можно считать излишними. Результаты анализа принципиального компонента и скорости получения вместе дают более глубокие представления о механизме реакции “иодных часов”.
    Notes: Abstract An updated mechanism for the Briggs-Rauscher reaction (also known as “Iodine Clock” reaction) has been investigated by the principal component analysis of the rate sensitivity matrix. The analysis revealed that five reactions of the 15-step model were redundant. The results of principal component and of rate-of-production analyses together gave an insight into the basic processes of the “Iodine Clock” reaction.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02070433
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  • 9
    Electronic Resource
    Electronic Resource
    Generation of model reactions leading to limit cycle behavior (1982)
    Springer
    Reaction kinetics and catalysis letters 18 (1982), S. 65-71 
    Details
    ISSN: 1588-2837
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Abstract Была обобщена система дифференциальных уравнений Феистеля и Эбелинга. Были рассмотрены некоторые новые случаи формальной кинетики с двумя внутренними компонентами, которые представляют собой граничное циклическое поведение. На основе численного интегрирования детерминистических моделей этих реакций был подтвержден осциллирующий нарактер систем.
    Notes: Abstract The system of differential equations by Feistel and Ebeling has been generalized. Some new formal kinetic reactions with two internal components, which may exhibit limit cycle behavior have been studied. Based upon the numerical integration of the deterministic models of these reactions the oscillatory character of the systems has been confirmed.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02065139
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  • 10
    Electronic Resource
    Electronic Resource
    The method of quasi-stationary sensitivity analysis (1988)
    Springer
    Journal of mathematical chemistry 2 (1988), S. 401-409 
    Details
    ISSN: 1572-8897
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mathematics
    Notes: Abstract A new sensitivity analysis technique is developed by utilizing Tihonov's singular perturbation theory. The described sensitivity analysis method deals with algebraic equations instead of solving the system of differential equations, which is the case in conventional sensitivity analysis. In the held of chemical kinetics, the proposed technique can supply information on the importance ofelemcntarv steps in complex reaction mechanisms. As examples, high-temperature propane pyrolysis and the chemistry of the “unpolluted” troposphere are studied.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01166303
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