ISSN:
0018-019X
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The N2-molecule-aryl-cation pair formed as the first intermediate in dediazoniations of arenediazonium ions can be trapped with CO in H2O with formation of the corresponding arenecarboxylic acids. This reaction is considered as a model for the reverse of dediazoniation, since CO is isoelectronic with N2. The evaluation of the yields of arenecarboxylic acids formed from substituted benzenediazonium ions using Taft's dual substituent parameter treatment demonstrates that the field reaction constant pF and the resonance reaction constant pR are positive and negative, respectively, as expected for a reaction which corresponds electronically to the addition of N2 to aryl cations.
Additional Material:
2 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hlca.19880710303
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