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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Langmuir 5 (1989), S. 1288-1292 
    ISSN: 1520-5827
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 101 (1994), S. 3230-3233 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Near-edge x-ray absorption fine structure spectroscopy was used to study the effect of temperature on ion pairing of a potassium salt in a modified carbonate (MC3) solution and in a poly(ethylene oxide)-potassium salt complex that used MC3 as a plasticizer. The modified carbonate was made by attaching three ethylene oxide units to the four position of ethylene carbonate. Spectra were obtained, at the K edge of potassium, over the temperature range of 25–110 °C. Studies of reference systems showed a correlation between ion pairing and white line splitting in the near-edge region of the spectra. The degree of white line splitting was used as a qualitative indicator of the degree of ion pairing as a function of temperature. The results indicate that, in both systems, the number of ion pairs increases with increasing temperature.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 69 (1996), S. 194-196 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Hard x rays from a synchrotron source were utilized in diffraction experiments which probed the bulk of electrode materials while they were operating in situ in battery cells. Two technologically relevant electrode materials were examined; an AB2-type anode in a nickel–metal–hydride cell and a LiMn2O4 cathode in a Li-ion "rocking chair'' cell. Structural features such as lattice expansions and contractions, phase transitions, and the formation of multiple phases were easily observed as either hydrogen or lithium was electrochemically intercalated in and out of the electrode materials. The relevance of this technique for future studies of battery electrode materials is discussed. © 1996 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Chester : International Union of Crystallography (IUCr)
    Journal of synchrotron radiation 6 (1999), S. 596-598 
    ISSN: 1600-5775
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Geosciences , Physics
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Mathematical programming 59 (1993), S. 325-343 
    ISSN: 1436-4646
    Keywords: Composite functions ; nonsmooth programming ; multi-objective problems ; necessary and sufficient conditions ; scalarizations
    Source: Springer Online Journal Archives 1860-2000
    Topics: Computer Science , Mathematics
    Notes: Abstract This paper examines nonsmooth constrained multi-objective optimization problems where the objective function and the constraints are compositions of convex functions, and locally Lipschitz and Gâteaux differentiable functions. Lagrangian necessary conditions, and new sufficient optimality conditions for efficient and properly efficient solutions are presented. Multi-objective duality results are given for convex composite problems which are not necessarily convex programming problems. Applications of the results to new and some special classes of nonlinear programming problems are discussed. A scalarization result and a characterization of the set of all properly efficient solutions for convex composite problems are also discussed under appropriate conditions.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Meteorology and atmospheric physics 61 (1996), S. 153-186 
    ISSN: 1436-5065
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geography , Physics
    Notes: Summary A coupled ocean-atmosphere anomaly model has been developed for simulating ENSO cycle and its mechanism-study in this paper. After a long model run, the coupled model is successful in demonstrating ENSO-like irregular interannual variability and corresponding horizontal spatial structures. Based on the simulated results, the dynamics and the thermodynamics of the model ENSO cycle have been investigated, and in particular the negative feedback mechanisms that act to oppose instability of air-sea interaction, inducing termination of warm and cold events, have been examined. A detailed analysis of the oceanic wave dynamical properties and heat budget of the SST changes in a representative cycle suggest that the negative feedback mechanism to check the unstable growth of a warm event obviously differs from that of a cold event. The mechanism that induces decay and termination of a cold event is closely related to the negative, delayed feedback effect produced by the oceanic dynamical wave reflection at the western boundary. However, independent of the wave reflection effect, the negative feedback mechanism by which the coupled system returns from a warm event is associated with a slowly eastward-propagating coupling mode. Accompanied with the strong unstable development of the equatorial positive SST anomaly, the anomalous upwelling of cold water generated off the equator and the nonlinear anomalous meridional advection generated in the equator west of instability area jointly restrain the instability and finally plunge the system from a mature warm phase into a weak cold phase. A comparison between the results from the present model and the previous works is also discussed in this paper.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Meteorology and atmospheric physics 62 (1997), S. 161-177 
    ISSN: 1436-5065
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geography , Physics
    Notes: Summary By using a coupled ocean-atmosphere model with an oceanic surface boundary layer, including linear atmospheric and oceanic dynamics and linearized SST prognostic equation with respect to spatially varying climatological background states, we have investigated the eigenvalue problem of the linearized coupled system in the tropical Pacific, including the characteristic periods, horizontal structures, temporal-spatial evolution and instability of the unstable interannual oscillation characteristic modes and their associations with ENSO. The main results show that the quasi-biennial (QB) oscillation was found to act as the most unstable mode in the tropical Pacific coupled air-sea system. Only the most unstable QB mode displays the ENSO-like structure and temporalspatial evolution, and its existence seems likely to have no essential dependence on the climatological annual cycle (AC). Unfortunately, from the linearized coupled system we have not derived a most unstable mode relevant to the observed principle mode with the preferred 3–4 year lower-frequency (LF) oscillation period in the real world ENSO variability. Therefore, we infer that the LF mode would likely result from certain nonlinear interaction, in which the QB mode that acts as the shortest ENSO cycle could be fundamentally important. Also, we believe that the results in present work could be helpful to fully understand the multiple time scales and the associated mechanism responsible for the real world ENSO variability.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Journal of optimization theory and applications 82 (1994), S. 173-180 
    ISSN: 1573-2878
    Keywords: Second-order upper Dini-directional derivative ; secondorder characterizations ; convex function
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics
    Notes: Abstract We introduce a second-order upper Dini-directional derivative and obtain a second-order characterization for a continuously Gâteaux differentiable function to be a convex function.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Journal of optimization theory and applications 86 (1995), S. 631-648 
    ISSN: 1573-2878
    Keywords: Convex composite minimization problems ; generalized second-order directional derivatives ; generalized Taylor expansions ; basic constraint qualifications ; second-order optimality conditions
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics
    Notes: Abstract In this paper, we present second-order optimality conditions for convex composite minimization problems in which the objective function is a composition of a finite-valued or a nonfinite-valued lower semicontinuous convex function and aC 1,1 function. The results provide optimality conditions for composite problems under reduced differentiability requirements.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Journal of optimization theory and applications 89 (1996), S. 483-491 
    ISSN: 1573-2878
    Keywords: Simplexes ; convex sets ; convex programs
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics
    Notes: Abstract In this note, necessary and sufficient conditions are given for the intersection of them−1 simplex co {ξ1,...,ξ m } ofm affinely independent vectors ξ1,...,ξ m of ℝ n and the negative orthant ℝ − n to be empty, i.e., $$co\{ \xi ^1 ,...,\xi ^m \} \cap \mathbb{R}_ - ^n = \emptyset ,$$ wherem≤n. It is also shown that the special casem=2 can be checked easily. These results suggest that the above-mentioned emptiness can be checked recursively. Some numerical examples are given to illustrate the results. Potential applications of these results include the compatible multicommodity flow problems and satisficing solution problems.
    Type of Medium: Electronic Resource
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