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  • Articles: DFG German National Licenses  (2)
  • Electronic Resource  (2)
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  • Articles: DFG German National Licenses  (2)
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  • Electronic Resource  (2)
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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Hyperfine interactions 60 (1990), S. 651-653 
    ISSN: 1572-9540
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The perturbation function of a Cd probe atom bound in a hydrogen-decorated vacancy complex in Pt is found to exhibit dynamical relaxation at 294 K, as measured by the technique of perturbed γ-γ angular correlations. Based on other characteristics of the complex, a model is proposed for the structure of the complex. In the undecorated state, it consists of a probe atom at the center of a tetrahedron of vacancies in the fcc structure. In the decorated state at low temperature, the probe atom returns to one of the four vacant lattice sites. The relaxation at room temperature is attributed to motion of the probe atom in a cage formed by the four vacant sites.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1572-9540
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract In previous work, we introduced hydrogen (H) into Ni and Pt metals at room temperature by electrolysis. To study H-vacancy interactions on an atomic scale, trapping of diffusing H atoms at impurity-vancancy complexes was detected using perturbed γ-γ angular correlations. Two new results are reported here: (1) Transformation rules are clarified between undecorated and H-decorated complexes which are detected after annealing Pt at 323 K. In addition, non-cubic In sites were observed to form by chargingannealed, Pt, which are attiributed either to H atoms at random in the lattice or to precursor nuclei of a Pt hydride. (2) NiH is observed to form under cathodic charging of Ni at high current densities, and detected by growth of a nonmagnetic, cubic metastable phase.
    Type of Medium: Electronic Resource
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