ISSN:
0749-1581
Keywords:
1H and 13C NMR
;
Phenyldibenzophospholes
;
assignment, computer simulation
;
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Proton and 13C NMR parameters have been determined for phenyldibenzophosphole and its oxide, sulfide, selenide and W(CO)5 complex from high-resolution one- and two-dimensional (COSY, HETCOR and 2DJ) experiments at 4.7, 7.1 and 9.4 tesla. Assignments of chemical shifts and coupling constants have been made and verified by computer simulation of the proton spectra. The data are discussed in relation to the geometry and electron density at phosphorus and the diamagnetic anisotropy of the W(CO)5 group.
Additional Material:
4 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/mrc.1260250908
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