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  • Artikel: DFG Deutsche Nationallizenzen  (7)
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  • Artikel: DFG Deutsche Nationallizenzen  (7)
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Erscheinungszeitraum
Schlagwörter
  • 1
    Digitale Medien
    Digitale Medien
    Berkeley, Calif. : Berkeley Electronic Press (now: De Gruyter)
    International journal of chemical reactor engineering 3.2005, 1, A29 
    ISSN: 1542-6580
    Quelle: Berkeley Electronic Press Academic Journals
    Thema: Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Heterogeneous kinetics of catalytic wet air oxidation (CWAO) of phenol was studied using copper supported on activated carbon as the catalyst and oxygen as the oxidant. Both mass transfer effect and deactivation of catalyst can affect the kinetics measurement. To eliminate the mass transfer barriers, the study was conducted in a stirred tank batch reactor using catalysts of very small particle size. In order to prevent the catalyst deactivation caused by copper leaching from the support, saturated pH buffer solution was added into the reaction system and the initial phenol and catalyst concentrations were reduced. A mathematic model was proposed following the Langmuir-Hinshelwood mechanism to simulate the reaction kinetics. It is believed through simulation that the dissolved oxygen is adsorbed by the catalyst in molecular form which subsequently starts to degrade phenol on the catalyst surface. Both reaction rate constant and activation energy were determined for a temperature range of 140 - 160 oC and an oxygen partial pressure range of 0.4 - 1.6 MPa. The proposed mechanism and kinetic model were found to be in good agreement with experimental results.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    s.l. : American Chemical Society
    Langmuir 9 (1993), S. 2530-2536 
    ISSN: 1520-5827
    Quelle: ACS Legacy Archives
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 3
    Digitale Medien
    Digitale Medien
    s.l. : American Chemical Society
    Langmuir 10 (1994), S. 3296-3302 
    ISSN: 1520-5827
    Quelle: ACS Legacy Archives
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 4
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 39 (1993), S. 1628-1640 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The heterogeneous macropore, surface and micropore diffusion model recently proposed by Hu et al. (1993) for single-component systems is exiended to multicomponent systems in the description of sorption kinetics of gaseous adsorbates in bidispersed (macropore and micropore diffusions), heterogeneous microporous particles. This model describes sorption of gaseous adsorbates with allowance for the energy distribution of adsorption site for both equilibrium and diffusion of the adsorbed species. A uniform distribution is used to describe this energy distribution, and the cumulative energy distribution function is assumed the same for all species in the analysis of multicomponent mixtures. Extensive experimental data of ethane and propane in Ajax activated carbon are collected to study the effects of energy distribution on the binary adsorption, desorption, and displacement dynamics.
    Zusätzliches Material: 15 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 5
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 41 (1995), S. 1585-1592 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 6
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 39 (1993), S. 249-261 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: In this article, we present a model to describe sorption kinetics of gaseous adsorbates onto bidispersed heterogeneous microporous particles. This model describes adsorption and desorption of gaseous adsorbates with allowance for the energy distribution of adsorption site for both equilibrium isotherm and diffusion of the adsorbed species. The adsorbed species of all energy level diffuse in two directions inside the particle. One direction is the direction along the particle coordinate while the other is the direction perpendicular to the particle coordinate (that is, the direction into the grain of the solid). This model is more fundamental than models previously proposed by Do and coworkers. Effects of energy distribution on the adsorption and desorption dynamics are investigated. Extensive experimental analysis of adsorption and desorption dynamics of ethane and propane onto Ajax activated carbon are carried out to validate this theory.
    Zusätzliches Material: 10 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 7
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 41 (1995), S. 1581-1584 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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