Electronic Resource
College Park, Md.
:
American Institute of Physics (AIP)
The Journal of Chemical Physics
95 (1991), S. 1530-1536
ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
The optical absorption spectra of acetone and acetone-d6 in the 3s Rydberg region have been remeasured and reanalyzed. Activity is observed in the a1 CH3 deformation, CH3 rock, and CC stretching vibrations, as before. The two low frequency displacement subbands of the transition, +250 and +309 cm−1 have been reassigned; the former is twice the a2 CH3 torsion, the latter cannot be assigned. Possible photophysical implications of the large frequency shifts in the methyl-centered modes are discussed.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.461067
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