ISSN:
1572-901X
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Summary Eighteen new coordination compounds are reported with diglyme (dgm) and pentaglyme (pgm) as ligands:viz. [M(dgm)2](SbCl6)2 with M=MgII, CaII, SrII, MnII, FeII, CoII, NiII, CuII, and ZnII; [M(pgm)](SbCl6)2 with M=MnII, FeII,CoII, NiII, CuII, and ZnII; and [M(pgm)](SbCl6)2 · H2O with M=MgII, CaII, and SrII. The metal(II) ions are hexacoordinated by the ether-oxygens of two diglyme molecules or of one pentaglyme molecule. The coordinated diglyme molecules are in the TGTT¯GT conformation.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00620748
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