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Calculation of rydberg states of lithium isoelectronic sequence (1986)

Kundu, B. ; Mukherjee, P. K.

Springer

Theoretical chemistry accounts 69 (1986), S. 51-62

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ISSN: 1432-2234

Schlagwort(e): Rydberg states ; Atomic wavefunctions ; Lithium atom

Quelle: Springer Online Journal Archives 1860-2000

Thema: Chemie und Pharmazie

Notizen: Abstract The transition energies and singly excited P, D and F states of Li, Be+ and B2+ for the Rydberg levels 1s 22s: 2 S→1s 2 nl: 2L (n=5, 6,...9) have been calculated using time dependent coupled Hartree-Fock (TDCHF) theory. Within single particle model the theory includes RPA type correlations and furnishes reasonable description of the excited states. The transition energies and oscillator strengths for allowed transitions are in good agreement with the experimental and theoretical values, wherever available. Effective quantum numbers have been estimated for all transitions.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1007/BF00526292

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