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Supramolecular Assemblies of 1,2-Dicarbadodecaborane(12) with Bowl-Shaped Calix[5]arene (1999)

Hardie, Michaele J. ; Raston, Colin L.

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 1999 (1999), S. 195-200

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Details

ISSN: 1434-1948

Schlagwort(e): Calixarene ; Carboranes ; Host-guest chemistry ; Non-classical hydrogen bonding ; Supramolecular chemistry ; Chemistry ; General Chemistry

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie

Notizen: Treatment of globular 1,2-dicarbadodecaborane(12) (o-carborane) 1 with the bowl-shaped container molecule calix[5]arene 2 affords either the crystalline 1:1 or 1:2 host-guest complexes (o-carborane)(calix[5]arene)(CH2Cl2) 3, (o-carborane)(calix[5]arene)(toluene) 4 and (o-carborane)(calix[5]arene)2(CH2Cl2)0.55. The three complexes show a remarkable range of different supramolecular interplay beyond the common structural unit, a ball-and-socket nano-structure or supermolecule [(o-carborane)∩(calix[5]arene)]. Complex 3 forms dimeric [(o-carborane)∩(calix[5]arene)]2 units, and 5 has an additional edge on interaction between the supermolecule and a secondary calix[5]arene host.

Zusätzliches Material: 8 Ill.

Materialart: Digitale Medien

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