ISSN:
1572-9028
Keywords:
cobalt based catalysts
;
syngas chemistry
;
mechanistic studies
;
CO disproportionation
;
acetaldehyde temperature programmed desorption
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Syngas reaction mechanism studies on cobalt based catalysts suggested that the CO dissociation step and the (alcohol and/or hydrocarbon) chain growth can be well mimicked by CO disproportionation and temperature programmed desorption (TPD) of acetaldehyde. Correlation between C2+ hydrocarbon selectivity and CO disproportionation on the one hand, C2+ alcohol selectivity and TPD after acetaldehyde adsorption on the other hand could be evidenced.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01491960
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