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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Environmental science & technology 25 (1991), S. 1174-1178 
    ISSN: 1520-5851
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Energy, Environment Protection, Nuclear Power Engineering
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 70 (1966), S. 2450-2455 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 356 (1992), S. 137-140 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] PCBs, first manufactured in 1929, were not reported in environmental samples until 1966. Their industrial use has been restricted in Europe and North America since the 1970s2'8. Even today, however, PCB concentrations in biota are high enough to be implicated in causing adverse reproductive ...
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Archives of environmental contamination and toxicology 25 (1993), S. 346-352 
    ISSN: 1432-0703
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Medicine
    Notes: Abstract A large selection of polychlorinated biphenyl (PCB) congeners was determined in tissues from several British bird species including three sea birds, four birds of prey, and herons (Ardea cinerea). The congener “signatures” were consistent between different tissues of the same individual, but varied within and between species. Congeners 138, 153, and 180 were dominant in most samples. Nevertheless, ∑PCB values were wide ranging (0.02–105 μg/g wet weight) and also differed considerably in subsamples of different tissues from individual birds. Applying recently reported toxicity equivalency factors (TEFs) for non-ortho, mono-ortho, and di-ortho substituted PCBs to liver concentrations of such congeners, it appears that the mono-ortho congeners 105 and 118 make a high contribution to TEFs when their toxicities are weighted by concentration. The study highlights that caution is needed when interpreting data on contaminants in wildlife, but suggests that careful sampling will reduce the many variables which can give rise to differing congener patterns and ∑PCB values.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Biogeochemistry 7 (1989), S. 3-10 
    ISSN: 1573-515X
    Keywords: gold ; humates ; humic acid ; cycling in soils ; plant uptake
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract An experiment in which perennial ryegrass (Lolium perenne L.) was grown in solution cultures containing various forms of radioactive gold (198Au) is described. Uptake of labelled Au from solutions containing either Au chloride or various Au-humic acid (HA) complexes is compared. In each case concentrations of Au in the plant roots were several fold higher than in the plant shoots. However, the Au concentration in roots from some of the Au-HA preparations was only about 5% of that from the Au-HA solutions. High voltage electrophoresis studies indicate the presence of several Au-HA complexes in the solution cultures. The relevance of these findings to the cycling of Au within soils is discussed.
    Type of Medium: Electronic Resource
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  • 6
    ISSN: 1573-5036
    Keywords: Fulvic acids ; Humic acids ; Lolium perenne L. ; Silver
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary An experiment in which perennial ryegrass (Lolium perenne L.) was grown in solution cultures containing various forms of radiosilver (110mAg) is ptake of labelled Ag from solutions containing either AgNO3, Ag2SO4, AgCH3COO, Ag-humic acid (HA) or Ag-fulvic acid (FA) complexes is compared. In each case concentrations of Ag in the plant roots was several fold higher than in the plant shoots. However the Ag concentration in roots from the Ag-HA preparations was only about 5% of that from the AgNO3 solutions; from Ag-FA it was 18%. Transport index values were highest for plants grown in the Ag-HA solution, indicating greater mobility of Ag within these plants. Preliminary data for a selective extraction procedure performed on Ag-HA preparations suggest sorption onto various active sites. The relevance of these findings to the cycling of Ag within soils is discussed.
    Type of Medium: Electronic Resource
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  • 7
    ISSN: 1573-2932
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A reconnaissance survey was made of trace metals in surface waters and three aquatic bryophytes (Scapania undulata,Hygrohypnum luridum andPolytrichum commune) in the mid-Wales Ag-Pb mining district. This area is contaminated by heavy metals from past mining. Elevated levels of Ag, Cd, Cu, Pb, and Zn were found in water and plant tissue. All the plants accumulated Ag and the other metals butScapania appears the most suitable as a plant monitor of Ag-polluted waters.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Water, air & soil pollution 33 (1987), S. 179-189 
    ISSN: 1573-2932
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The potential use of honey as an indicator in mineral prospecting and environmental contamination studies has been investigated. Silver, Cd, Cu, and Pb levels are reported in honeys collected throughout the U.K. The elemental content of honeys was investigated in relation to that in the soils collected from within the foraging area. For samples collected over two seasons the following concentrations were found Ag 〈0.1 to 6.5 ng g−1 (d.w.); Cd 〈0.3 to 300 ng g−1; Cu 35 to 6510 ng g−1; Pb 〈2 to 200 ng g−1. Considerable spatial and seasonal fluctuations were apparent. No correlations were observed between honey and soil concentrations for either Cu or Pb. It is concluded that the low concentrations of heavy metals in honey and their inherent variability (due to differences in floral source, foraging range, entrapment of atmospheric particulates on the flower, etc.) detract from the reliable use of honey as a monitoring tool. The relative merits of honeybees, pollen and beeswax for environmental monitoring or biogeochemical prospecting studies are also briefly discussed.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Environmental geochemistry and health 5 (1983), S. 122-127 
    ISSN: 1573-2983
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Medicine
    Notes: Abstract In west and north Wales silver was mined extensively between 1750 and 1900, where it was frequently present as its sulphide form, argentite, whilst also occurring as a guest element in galena and sphalerite. Determination of the silver content of a range of soil types from areas devoid of mines by flameless atomic absorption spectrometry established normal background levels. Soils derived from black shales, or rich in organic matter were inherently richer in silver than the sandstone or limestone derived soils examined. Soils once exposed to contamination from the mining activities of the 19th Century can still be identified as they show elevated levels of silver. Fluvially derived contamination is confined to valley floodplains, but aerial transportation of mine spoil wastes enhance metal levels around derelict mine sites. Spoil analysed from areas of different geology contained a range of silver values reflecting variations in ore type, grain size and technique of ore extraction.
    Type of Medium: Electronic Resource
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  • 10
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Evaporative light scatering detection ; APCI mass spectrometry ; Triacylglycerols
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Short- and long-chain triacylglycerols (SLCT) are a family of lipids prepared by chemical or enzymatic interesterification of triacetin, tripropionin and/or tributyrin, and long-chain (C16!18) hydrogenated vegetable oils. In this study, a normal-phase cyanopropyl high-performance liquid chromatographic (HPLC) method was developed for the separation and quantification of SLCT. The method is capable of separating SLCT mixtures, free fatty acids and the neutral lipid classes of saturated long-chain triacylglycerols, diacylglycerols and monoacylglycerols. To characterize the specific SLCT classes, a normal-phase HPLC procedure using a non-modified silica column was developed to separate the SLCT into individual isomers based on total carbon number and position of fatty acids on the glycerol backbone. Online coupling with a mass detector (LC/MS) allowed the identification of the individual triacylglycerol structures.
    Type of Medium: Electronic Resource
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