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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Analytical chemistry 53 (1981), S. 1021-1023 
    ISSN: 1520-6882
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of solution chemistry 10 (1981), S. 155-162 
    ISSN: 1572-8927
    Keywords: Acidic dissociation ; basic dissociation ; Bis ; dissociation constant ; ionization constant ; methanol ; solute-solvent effects ; solvent effect
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The solvent effect on the acidic dissociation of the protonated base tris(hydroxymethyl)aminomethane (Tris) has been studied in aqueous mixtures of several organic constituents with qualitatively similar results. The dissociation constant of protonated 2-amino-2-methyl-1,3-propanediol (Bis), the analog of Tris with two hydroxy groups, has now been determined in 50 mass % methanol by emf measurements of cells without liquid junction in the temperature range 10 to 40°C. The conventional treatment of the data indicated abnormally low values for the activity coefficient of BisHCl, but an alternate method of calculation with allowance for ion pairing provided no advantage. The pKa in the range from T=283.15 to 313.15 K is given by $$pK_a = 3755.63/T - 24.5127 + 3.56855 In T$$ with a standard deviation of 0.0006 at the seven temperatures. Thermodynamic quantities for the dissociation process and corresponding quantities for the transfer from water to 50 mass % methanol were derived. The implications of the results in terms of selective solute-solvent stabilization are discussed.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 25 (1983), S. 559-568 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Potentiometric and amperometric measurements were made with microbial fuel cells containing E. coli or yeast as the anodic reducing agent and glucose as the oxidizable substrate. The catalytic effects of thionine and resorufin on the anode reaction were investigated. Results on the potentiometry, polarization, and coulombic output of the cells support a mediator-coupled mechanism for the transfer of electrons from the organism to the electrode in preference to a mechanism of “direct” electrochemical oxidation of glucose or its degradation products. Experiments with 14C-labeled glucose show that when a microbial fuel cell produces a current under load, exogenous glucose is metabolized to produce 14CO2. The Coulombic yields of the cells indicate a high degree of energy conversion in these systems.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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