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Digitale Medien

The reactive states of ions: Dimethyl-hexadienes and tetramethylcyclobutenes (1975)

Rennekamp, Michael E. ; Hoffman, Michael K.

Chichester : Wiley-Blackwell

Biological Mass Spectrometry 10 (1975), S. 1067-1074

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Details

ISSN: 0030-493X

Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie

Notizen: The principal decomposition routes of molecular ions of cis, cis-3,4-dimethyl-2-4-hexadiene, cis, trans-3,4-dimethyl-2,4-hexadiene, cis-1,2,3,4-tetramethylcyclobutene and trans-1,2,3,4-tetramethylcyclobutene were studied using ion kinetic energy spectroscopy. Evidence indecates that loss of radicals from [M]+· appears to proceed via an electronically excited state, while loss of a neutral molecule appears to involve complete equilibration of structure within the system, or may involve both ground state and excited state pathways.

Zusätzliches Material: 2 Tab.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/oms.1210101204

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