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  • 1990-1994  (5)
  • 1991  (5)
Material
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  • 1990-1994  (5)
Year
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Computational mechanics 7 (1991), S. 329-339 
    ISSN: 1432-0924
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract A formulation for incorporating two singular points (TSP) of variable orders in a single finite element is presented. Though the element does not satisfy any of the convergence criterion, its performance is found to be good, which has been demonstrated by considering number of examples on kinked cracks. In each case only one such element is incorporated in the whole discretization. These examples illustrate the usefulness of the element to analyse kinked cracks of various sizes and shapes and subjected to different loading and boundary conditions. Computed J-integrals are compared with analytical solutions, wherever possible, and the accuracy appears quite good. Effect of size of the element on, and the path independence of, J are also examined.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 189 (1991), S. 51-61 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Durch Kondensation von 3-Nitrophthalsäureanhydrid mit 4,4′-Diaminodiphenylether und anschließende Reaktion mit Bisphenol-A wurde ein Diamin erhalten, das mit Maleinsäure zu einem Ethergruppen enthaltenden Bismaleimid-Monomeren umgesetzt wurde; dieses wurde mittels Elementaranalyse, IR-und NMR-Spektroskopie charakterisiert. Es ist in niedrigsiedenden Lösemitteln sehr gut löslich und vernetzt bei Temperaturen oberhalb 200°C. Das ausgehärtete Produkt ist in allen Lösemitteln unlöslich, einschließlich konz. H2SO4. Das thermische Verhalten des Bismaleimids wurde durch TGA, DTA und isotherme Alterung untersucht; das Polymere ist stabil bis 300°C.
    Notes: A bismaleimide monomer containing etherimide linkages was synthesized from 3-nitrophthalic anhydride, diamino diphenyl ether and bisphenol-A by the principle of activated nucleophilic displacement reaction and finally reacting the produced diamine with maleic anhydride. The monomer was characterized by elemental analysis, IR and NMR spectroscopy. It is highly soluble in low boiling solvents such as chloroform, tetrahydrofuran, etc. It forms a cross-linked polymer on heating to 200°C and higher. The cured product is completely insoluble in usual solvents including conc. H2SO4. The thermal behaviour of the bismaleimide was studied by TGA, DTA and isothermal aging. The polymer is stable up to 300°C. Laminates prepared with this resin and carbon fiber are almost void-free and possess good mechanical and thermal properties. These properties are compared with earlier reported bismaleimide imide prepolymer based composite.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 42 (1991), S. 3101-3110 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Tensile and impact behavior of CaCO3-filled polypropylene was studied in the composition range 0-60 wt % filler. Tensile modulus increased while tensile strength and breaking elongation decreased with increase in CaCO3 content. The modulus increase and elongation decrease were attributed to increased filler-polymer interaction resulting in reduction in molecular mobility, while increased amorphization and obstruction to stress transfer accounted for the tensile strength decrease. Analysis of tensile strength data showed introduction of stress concentration in the composites. Izod impact strength at first increased up to a critical CaCO3 content, beyond which the value decreased. Surface treatment of CaCO3 with a titanate coupling agent LICA 12 enhances the adhesion of the filler and polymer, which further modifies the strength properties. Scanning electron microscopic studies indicated better dispersion of CaCO3 particles upon surface treatment, which effected the changes in the strength properties of the composites.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 43 (1991), S. 1891-1900 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A study of melt rheology of the blend of styrene-acrylonitrile (SAN) and polypropylene (PP) in composition range 0-50 wt % SAN content is presented. Measurements are made on a capillary rheometer at temperatures of 210, 230, and 250°C. The data are presented as flow curves and variations of melt viscosity and melt elasticity as functions of shear rate and blend composition. Scanning electron micrographs are presented to illustrate the dispersion and other characteristics of the SAN droplets. Results of melt rheology are interpreted in terms of the role of SAN droplets in the blend.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 43 (1991), S. 311-328 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Polybutylene terephthalate (PBT) is a commercially successful thermoplastic polyester but has certain drawbacks such as low impact strength and low melt strength. An attempt has been made to modify the properties of PBT by blending it with polyolefin such as highdensity polyethylene (HDPE). Since PBT and HDPE are incompatible, an ionomer has been used as a compatibilizer to form an alloy. Alloys of PBT and HDPE with varying amounts (2-8%) of ionomer were prepared by melt blending. The ultimate mechanical properties improved significantly on the addition of the ionomer due to an increase in interfacial adhesion between PBT and HDPE. DSC studies show that the presence of ionomer facilitated the crystallization of PBT in the alloy. DMTA studies show that more of PBT (amorphous) is going in to the HDPE-rich phase in the presence of ionomer. The morphology of the alloys was studied using scanning electron microscopy (SEM), polarizing microscopy (PM), and small-angle light scattering (SALS). They showed improved dispersion of HDPE domains in PBT matrix with increasing ionomer content and change in the type of superstructure on adding the ionomer. It has been shown that an alloy of PBT and HDPE with improved mechanical properties and homogeneous morphology can be made with use of ionomer as a compatibilizer. Such alloys are cost effective and can find use in several engineering applications.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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