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  • 1990-1994  (2)
  • 1993  (2)
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  • 1990-1994  (2)
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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Hyperfine interactions 79 (1993), S. 749-753 
    ISSN: 1572-9540
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The binding of hydrogen in different vacancy complexes in platinum metal was investigated with atomic-scale sensitivity using perturbed angular correlations of gamma rays (PAC). Hydrogen was introduced by cathodic charging. Detrapping was monitored microscopically during desorption at 294 K by changes in site fractions of hydrogen-decorated and undecorated complexes. Analysis of desorption includes effects of retrapping of hydrogen at other sites. Assuming a trap concentration of 10−3, binding enthalpies of 0.23(2), 0.28(1), 0.24(1) and 〉0.20 eV are obtained for hydrogen atoms in 1V to 4V complexes, respectively. The small differences between the binding enthalpies demonstrate that hydrogen binding is insensitive to the detailed geometrical structure of small vacancy complexes. However, the magnitudes found here are a factor of two smaller than in the literature.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Hyperfine interactions 79 (1993), S. 755-760 
    ISSN: 1572-9540
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Annihilation reactions between mobile self-interstitial defects and complexes of vacancies with111In probe solutes in Au were studied. Measurements were made using the technique of perturbed angular correlations of gamma rays (PAC). Au samples were doped with complexes and plastically deformed at a low temperature to generate fluxes of self-interstitials. Changes in the concentrations of monovacancy (1V) to tetravacancy (4V) complexes induced by annihilation reactions were measured. These are now analysed using a system of coupled first-order equations in order to obtain interstitial annihilation cross sections of the complexes and the fractional amounts of different interstitial clusters in the flux. Relative cross sections obtained for Au are 1.0(1), 3.3(3), 1.2(2) and 7.5(2.5), respectively, for 1V to 4V complexes. The large increase in the cross sections with vacancy number is attributed to a progressive relaxation of the dilatational strain surrounding the oversized In solute as more vacancies are trapped. Also obtained from the analysis are values 0.34(5), 0.66(7), 0.0(1) and 0.0(2), respectively, for the fractions of mobile 1I to 4I clusters in deformed Au, indicating that di-interstitials are produced more readily than mono-interstitials during plastic deformation.
    Type of Medium: Electronic Resource
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