ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
This article discusses capillary forces measured by scanning force microscopy (SFM), which, as recently reported, show a discontinuous behavior at a low relative humidity between 20% and 40% depending on the solid surfaces. A capillary force discontinuity is very interesting in terms of a possible phase change or restructuring transition of bulk water in the interfacial solid–liquid region. Unfortunately, we have found that SFM measurements show an inherent weakness in the determination of the origin of the forces that are obtained during pull-off measurements. This article critically discusses the origin of the adhesive interactions as a function of relative humidity with chemically modified probing surfaces. Our measurements indicate that force discontinuities in pull-off measurements are strongly affected by the inability of the liquid to form capillary necks below a critical threshold in relative humidity. In the course of this article, we will discuss roughness effects on capillary forces and provide a modified capillary force equation for asperity nanocontacts. © 2001 American Institute of Physics.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.1331298
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