Electronic Resource
Oxford [u.a.]
:
International Union of Crystallography (IUCr)
Acta crystallographica
56 (2000), S. 22-23
ISSN:
1600-5759
Source:
Crystallography Journals Online : IUCR Backfile Archive 1948-2001
Topics:
Chemistry and Pharmacology
,
Geosciences
,
Physics
Notes:
The title octahedral complexes, [bis(pyridine-2-carbonyl)aminate]dichloro(methanol)iron(III), [Fe(C12H8N3O2)Cl2-(CH4O)], and [bis(pyridine-2-carbonyl)aminate]dichloro-(ethanol)iron(III), [Fe(C12H8N3O2)Cl2(C2H6O)], both crystallize in space group P\overline 1 and have similar structures. Monoanionic bpca− [bis(pyridine-2-carbonyl)aminate] acts as a planar tridentate ligand in both cases. Coordination bond distances are in the range typical of high-spin FeIII complexes. Carbon–oxygen distances are typical of a C=O double bond suggesting the negative charge of the bpca− ligand is localized on the central N atom.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1107/S010827019901272X
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