ISSN:
1600-5759
Source:
Crystallography Journals Online : IUCR Backfile Archive 1948-2001
Topics:
Chemistry and Pharmacology
,
Geosciences
,
Physics
Notes:
The structure of (11,12,24,25-tetrahydro-28,34-dimethoxy-3,6,16,19,31,37-hexamethyl-1,21[1′,3′]:8,14[1′′,3′′]-dibenzeno-10H,23H-tetrabenzo[f,h,o,z][1,5,10,14]tetraoxacyclooctadecane)lithium chloride monohydrate, anti-[Li(C50H48O6)]Cl·H2O, at 100 K reveals that the host is less strained than that of the syn-bridged isomer. There are two independent complex cations, each lying on a center of symmetry. Four short [1.944 (2)–1.998 (2) Å] and two long [2.381 (2) and 2.455 (2) Å] Li+...O distances provide six-coordination in a distorted octahedral environment.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1107/S0108270100005722
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