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  • 1
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 80 (2002), S. 1162-1164 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A full color display with its spectra covering the entire visible color range using a single polymer is presented here. Different concentrations of poly(2,6-[4-phenylquinoline]) and poly(2,6-[p-phenylene]-4-phenylquinoline) were incorporated into silica gels via the sol–gel technique. At high concentrations, the conjugated polymers form multiple excimers in the channels within the silica network, leading to the emission of red light (∼600 nm). At low concentrations, the polymer chains are isolated and are being trapped individually in the silica domain, which results in the emission of blue light (∼400 nm). For concentrations in-between, moderate extensive chain interaction leads to the emission of green, yellow, and orange colors. Therefore, the color tunability can be achieved by simply varying the concentration of quinoline polymers in the silica glasses. © 2002 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 59 (2000), S. 71-81 
    ISSN: 1572-8943
    Keywords: glass transition temperature ; hydrogen bonding ; kinetics of phase separation ; phase diagram ; poly(n-hexyl methacrylate) ; poly(styrene-co-vinyl phenol) ; TMDSC
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The thermally induced phase separation behavior of hydrogen bonded polymer blends, poly(n-hexyl methacrylate) (PHMA) blended with poly(styrene-co-vinyl phenol) (STVPh) random copolymers having various vinyl phenol contents, was studied by temperature modulated differential scanning calorimetry (TMDSC).The enthalpy of phase separation was determined to be about 0.5 cal g−1 for one of the blends. A phase diagram was constructed from the TMDSC data for one of the blends. The kinetics of phase separation was studied by determining the phase compositions from the glass transition temperatures of quenched samples after phase separation. Subsequently, the phase separated samples were annealed at temperatures below the phase boundary to observe the return to the homogeneous state.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 59 (2000), S. 541-546 
    ISSN: 1572-8943
    Keywords: crystallinity by DSC ; enthalpy relaxation ; glass transitional interval ; heat capacity ; melting below Tg ; physical aging ; PPO crystals
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Slow evaporation of toluene from poly(2,6-dimethyl-1,4-phenylene oxide), PPO, at 23°C produced crystals which melt between 185 and 265°C and have a crystallinityof 0.58. About 8 wt% of the crystals appear to melt temperatures below 220°C. The lattertemperature marks the end of the glass transition interval for this polymer.
    Type of Medium: Electronic Resource
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