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  • 2000-2004  (2)
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  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 112 (2000), S. 3967-3979 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We apply a statistical–thermodynamic approach to the study of a particular physical system (two sets of nonlinearly coupled oscillators), driven far away from equilibrium. Such a system displays a kind of complex behavior consisting in the so-called Fröhlich effect leading in steady-state conditions to a nonequilibrium phase condensation resembling the Bose–Einstein condensation of systems in equilibrium. A kind of "two-fluid model" arises: the "normal nonequilibrium phase" and Fröhlich condensate or "nonequilibrium superphase," which is shown to be an attractor of the system. We work out some aspects of the irreversible thermodynamics of this dissipative complex system. Particular nonlinear properties are discussed and Lyapunov exponents determined. This kind of system gives a good modeling of polar vibration modes in polymers and biopolymers. © 2000 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 112 (2000), S. 2692-2700 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: In the framework of a nonequilibrium statistical ensemble formalism, consisting of the so-called Nonequilibrium Statistical Operator Method, we discuss the question of the choice of the space of thermohydrodynamic states. We consider in particular the relevant question of the truncation of description (reduction of the dimension of the state space). A criterion for justifying the different levels of truncation is derived. It depends on the range of wavelengths and frequencies which are the relevant ones for the characterization, in terms of normal modes, of the thermohydrodynamic motion in a nonequilibrium open system. Applications to the cases of thermal-sensitive resins and of n-doped polar semiconductors are done, numerical results are presented, and experimental observation is discussed. © 2000 American Institute of Physics.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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